Oxidation of Cyclohexene and α-Pinene with O2-H 2 Mixture in the Presence of Supported Platinum or Palladium Catalysts | Sciact - CRIS-system of Boreskov Institute of Catalysis

Oxidation of Cyclohexene and α-Pinene with O2-H 2 Mixture in the Presence of Supported Platinum or Palladium Catalysts Full article

Journal

Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171

Output data

Year: 2003, Volume: 52, Number: 7, Pages: 1544-1551 Pages count : 8 DOI: 10.1023/A:1025688908667

Tags

α-pinene, Catalysis, Cyclohexene, Heteropoly compounds, Hydrogen, Oxidation, Oxygen, Palladium, Platinum

Authors

Kuznetsova N.I. ¹ , Kuznetsova L.I. ¹ , Kirillova N.V. ¹ , Pokrovskii L.M. ² , Detusheva L.G. ¹ , Ancel J.-E. ³ , Likholobov V.A. ¹

Affiliations

1	G. K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 5 prosp. Akad. Lavrent´eva, 630090 Novosibirsk, Russian Federation
2	N. N. Vorozhtsov Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 prosp. Akad. Lavrent´eva, 630090 Novosibirsk, Russian Federation
3	ARCHEMIS, 24 Jean Jaurès av., 69153 Decines Charpieu, Cédex, France

Funding (1)

Russian Foundation for Basic Research

00-15-97447

Oxidation of cyclohexene and α-pinene with an O2—H2 mixture in the catalytic systems containing Pt or Pd and heteropoly compounds (HPC) was studied. The main oxidation products are epoxides, allyl alcohols, and ketones. The highest yield of the oxidation products was obtained in the presence of the platinum catalyst in combination with HPC PW11 or PW11Fe. The reaction mechanism was proposed. A relationship between the HPC composition and the nature of intermediates involved in oxidation was examined.

Kuznetsova N.I. , Kuznetsova L.I. , Kirillova N.V. , Pokrovskii L.M. , Detusheva L.G. , Ancel J.-E. , Likholobov V.A.
Oxidation of Cyclohexene and α-Pinene with O2-H 2 Mixture in the Presence of Supported Platinum or Palladium Catalysts
Russian Chemical Bulletin. 2003. V.52. N7. P.1544-1551. DOI: 10.1023/A:1025688908667 WOS Scopus РИНЦ ANCAN OpenAlex

Кузнецова Н.И. , Кузнецова Л.И. , Кириллова Н.В. , Покровский Л.М. , Детушева Л.Г. , Ансель Ж.-Е. , Лихолобов В.А.
Окисление циклогексена и α-пинена смесью О2 -Н2 в присутствии катализаторов на основе нанесенных платины или палладия
Известия Академии наук. Серия химическая. 2003. №7. С.1462-1468. РИНЦ

Submitted:	Nov 25, 2002
Accepted:	Mar 11, 2003
Published print:	Jul 1, 2003

Web of science:	WOS:000185987400014
Scopus:	2-s2.0-1642532415
Elibrary:	13426262
Chemical Abstracts:	2003:715242
Chemical Abstracts (print):	140:183533
OpenAlex:	W54040821

DB	Citing
Web of science	3
Scopus	2
Elibrary	2
OpenAlex	2