Natural Compounds in the Synthesis of Chiral Organophosphorus Ligands | Sciact - CRIS-system of Boreskov Institute of Catalysis

Natural Compounds in the Synthesis of Chiral Organophosphorus Ligands Review

Journal

Russian Chemical Reviews
ISSN: 0036-021X , E-ISSN: 1468-4837

Output data

Year: 2003, Volume: 72, Number: 9, Pages: 803-822 Pages count : 20 DOI: 10.1070/RC2003v072n09ABEH000822

Tags

ASYMMETRIC HOMOGENEOUS HYDROGENATION; TRANSITION-METAL COMPLEXES; ENANTIOSELECTIVE CATALYTIC-HYDROGENATION; RHODIUM COMPLEXES; PHOSPHINE-LIGANDS; HIGHLY EFFICIENT; AMINO-ACIDS; CARBOHYDRATE PHOSPHINITES; ZINC ORGANOMETALLICS; DESIGNING CONCEPT

Authors

Tolstikov A.G. ¹ , Khlebnikova T.B. ² , Tolstikova O.V. ¹ , Tolstikov G.A. ³

Affiliations

1	Institute of Technical Chemistry, Urals Branch of the Russian Academy of Sciences, ul. Lenina 13-a, 614000 Perm, Russian Federation
2	G K Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, prosp. Acad. Lavrent'eva 5, 630090 Novosibirsk, Russian Federation
3	N N Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, prosp. Akad. Lavrent'eva 9, 630090 Novosibirsk, Russian Federation

Funding (1)

Council for Grants of the President of the Russian Federation

НШ-2020.2003.3

Methods for the synthesis of chiral organophosphorus compounds based on natural optically active compounds (hydroxy acids, amino acids and their derivatives, mono- and disaccharides, mono- and diterpenoids, steroids) are discussed. Particular attention is given to the synthesis of bisphosphines and bisphosphinites. These compounds serve as ligands for transition metal complexes, which catalyse asymmetric hydrogenation. Data on the enantioselectivity of hydrogenation of unsaturated precursors of amino acids and unsaturated prochiral acids as well as on information on the enantioselectivity of hydrosilylation of ketones are surveyed.

Tolstikov A.G. , Khlebnikova T.B. , Tolstikova O.V. , Tolstikov G.A.
Natural Compounds in the Synthesis of Chiral Organophosphorus Ligands
Russian Chemical Reviews. 2003. V.72. N9. P.803-822. DOI: 10.1070/RC2003v072n09ABEH000822 Scopus РИНЦ OpenAlex ANCAN

Толстиков А.Г. , Хлебникова Т.Б. , Толстикова О.В. , Толстиков Г.А.
Природные соединения в синтезе хиральных фосфорорганических лигандов
Успехи химии. 2003. Т.72. №9. С.902-922. WOS Scopus РИНЦ

Submitted:	Dec 30, 2002
Published print:	Sep 30, 2003
Published online:	Oct 17, 2007

≡ Scopus:	2-s2.0-12344329462
≡ Elibrary:	13443628
≡ OpenAlex:	W2161416948
≡ Chemical Abstracts:	2004:64777
≡ Chemical Abstracts (print):	140:253354

≡ Scopus	20	Сбор данных от 15.02.2026
≡ Elibrary	21	Сбор данных от 15.02.2026
≡ OpenAlex	30	Сбор данных от 15.02.2026