Potentiometric Monitoring of the State of Homogeneous Oxidation Catalysts Based on Heteropoly Acids Full article
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Russian Journal of Applied Chemistry
ISSN: 1070-4272 , E-ISSN: 1608-3296 |
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| Output data | Year: 2000, Volume: 73, Number: 5, Pages: 824-827 Pages count : 4 | ||
| Tags | alkylphenol; molybdenum; polyphosphate; quinone derivative; vanadium | ||
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Abstract:
The redox potentials E and pH values of 0.2 M aqueous solutions of H3+nPVnMo12-nO40 (HPA-n, 2 less than or equal to n less than or equal to 4) and products of their reduction with hydrazine hydrate to (H3+n+mPmMo12-nO40)-Mo-IV (HmHPA-n, 0 less than or equal to m less than or equal to n) were measured. It is proposed to use the dependences E =f(m) and pH = phi(m) as calibration curves for monitoring the degree of reduction m (m = [V-IV]/[H(m)HPA-n]) in oxidation of alkylphenols (2,6-dimethyl-phenol, 2,6-di-tert-butylphenol, and 2-methyl-1-naphthol) with HPA-n solutions into the respective alkyl-1,4-quinones.
Cite:
Zhizhina E.G.
, Odyakov V.F.
, Matveev K.I.
Potentiometric Monitoring of the State of Homogeneous Oxidation Catalysts Based on Heteropoly Acids
Russian Journal of Applied Chemistry. 2000. V.73. N5. P.824-827. WOS Scopus РИНЦ
Potentiometric Monitoring of the State of Homogeneous Oxidation Catalysts Based on Heteropoly Acids
Russian Journal of Applied Chemistry. 2000. V.73. N5. P.824-827. WOS Scopus РИНЦ
Original:
Жижина Е.Г.
, Одяков В.Ф.
, Матвеев К.И.
Потенциометрический контроль состояния гомогенных катализаторов окисления на основе гетерополикислот
Журнал прикладной химии. 2000. Т.73. №5. С.777-780. РИНЦ ANCAN
Потенциометрический контроль состояния гомогенных катализаторов окисления на основе гетерополикислот
Журнал прикладной химии. 2000. Т.73. №5. С.777-780. РИНЦ ANCAN
Dates:
| Submitted: | Oct 20, 1999 |
| Published print: | May 1, 2000 |
Identifiers:
| Web of science: | WOS:000089047000019 |
| Scopus: | 2-s2.0-0033799237 |
| Elibrary: | 13355987 |