31P, 17O, and 209Bi NMR Study of Tetrahydroxotetraoxohexabismuth(III) Di(2-ethylhexyl)phosphate | Sciact - CRIS-system of Boreskov Institute of Catalysis

31P, 17O, and 209Bi NMR Study of Tetrahydroxotetraoxohexabismuth(III) Di(2-ethylhexyl)phosphate Full article

Journal

Russian Journal of Inorganic Chemistry
ISSN: 0036-0236 , E-ISSN: 1531-8613

Output data

Year: 1998, Volume: 43, Number: 2, Pages: 252-255 Pages count : 4

Tags

HEXANUCLEAR COMPLEX

Authors

Fedotov M.A. ¹ , Yukhin Y.M. ² , Shubin A.A. ¹ , Udalova T.A. ²

Affiliations

1	Boreskov Institute of Catalysis Siberian Division Russian Academy of Sciences, pr. Akademika Lavrent'eva 5
2	Institute of Solid State Chemistry and Mineral Processing SB RAS

Multinuclear magnetic resonance (17O,31P, 209Bi) was used to study hydrolyzed bismuth-containing perchloric acid solutions and their extracts with di(2-ethylhexyl)phosphoric acid in organic solvents. The poly nuclear complex [Bi6O4(OH)4]6+ was characterized by 17O NMR. According to 31P NMR, extraction of this complex with a di(2-ethylhexyl)phosphoric acid solution resulted in its further condensation to form the {[Bi6O4(OH)4]R6}n complexes of definite composition.

Fedotov M.A. , Yukhin Y.M. , Shubin A.A. , Udalova T.A.
31P, 17O, and 209Bi NMR Study of Tetrahydroxotetraoxohexabismuth(III) Di(2-ethylhexyl)phosphate
Russian Journal of Inorganic Chemistry. 1998. V.43. N2. P.252-255. Scopus РИНЦ

Федотов М.А. , Юхин Ю.М. , Шубин А.А. , Удалова Т.А.
Исследование строения ди-2-этилгексилфосфата тетрагидроксотетраоксогексависмута(III) методом ЯМР 31P, 17O, 209Bi
Журнал неорганической химии. 1998. Т.43. №2. С.307-310. WOS Scopus РИНЦ ANCAN

Submitted:	May 17, 1996
Published print:	Feb 1, 1998

Scopus:	2-s2.0-2542532365
Elibrary:	13291479

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