Alkaline Hydrolysis of Keggin Heteropoly Acids in the Presence of Metal Carbonates | Sciact - CRIS-system of Boreskov Institute of Catalysis

Alkaline Hydrolysis of Keggin Heteropoly Acids in the Presence of Metal Carbonates Full article

Journal

Russian Journal of Inorganic Chemistry
ISSN: 0036-0236 , E-ISSN: 1531-8613

Output data

Year: 2000, Volume: 45, Number: 9, Pages: 1451-1452 Pages count : 2

Tags

CATIONS; NMR

Authors

Maksimov G.M. ¹

Affiliations

1	Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 5, Lavrent'ev prospect, Novosibirsk, 630090

The reactions of the heteropoly acids (HPAs) H3PM12O40 and H4SiM12O40 (M = Mo, V) in aqueous solutions with NL(II), Mg(TT), Co(II), Cu(n), Zn(II), Mn(II), Ca(II), Cd(II), La(III), and Ce(III) carbonates were studied by IR and P-31 NMR spectroscopy. The major reaction products are the complexes [(PM11O39)(2)Me](11)-and [(SiM11O39)(2)Me](12-) for La and Ce carbonates (Me is the metal ion from the carbonate) and [PM11MeO39](5)-and [SiM11MeO39](6-) for the other carbonates; the Me ions also function as the salt-forming cations.

Maksimov G.M.
Alkaline Hydrolysis of Keggin Heteropoly Acids in the Presence of Metal Carbonates
Russian Journal of Inorganic Chemistry. 2000. V.45. N9. P.1451-1452. WOS Scopus РИНЦ

Максимов Г.М.
Щелочной гидролиз гетерополикислот Кеггина в присутствии карбонатов металлов
Журнал неорганической химии. 2000. Т.45. №9. С.1586-1587. Scopus РИНЦ ANCAN

Submitted:	Jun 29, 1999
Published print:	Sep 1, 2000

Web of science:	WOS:000089606200026
Scopus:	2-s2.0-0042189861
Elibrary:	13349754

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