Reaction of Polynuclear Platinum Carbonyl with Tin(II) Chloride Full article
| Journal |
Russian Journal of Inorganic Chemistry
ISSN: 0036-0236 , E-ISSN: 1531-8613 |
||||
|---|---|---|---|---|---|
| Output data | Year: 2001, Volume: 46, Number: 3, Pages: 376-381 Pages count : 6 | ||||
| Tags | INORGANIC OLIGOMERS; COMPLEXES; DIANIONS; CLUSTERS; SPECTRA; Pt-195; SERIES; C-13NMR | ||||
| Authors |
|
||||
| Affiliations |
|
Abstract:
The H-2[Pt-3(CO)(6)](5) + SnCl2 reaction solutions and the precipitates isolated from these solutions were studied by IR and Mossbauer spectroscopy and NMR. At any initial reagent ratio in the range [Sn] : [Pt] = 1-5, the reaction yields a
Pt-Sn-CO cluster with the atomic ratio Sn : Pt = 1 : 1. The adsorption properties of the platinum-tin-carbonyl cluster were examined. Strong adsorption of the cluster on γ -Al2O3 and its high stability in contact with the supporter allow to use it as a precursor of supported bimetallic Pt-Sn/γ-Al2O3 catalysts and to prepare catalysts of the adsorption type of definite compositions.
Cite:
Shitova N.B.
, Perfilʹev Y.D.
, Alʹt L.Y.
, Savelʹeva G.G.
Reaction of Polynuclear Platinum Carbonyl with Tin(II) Chloride
Russian Journal of Inorganic Chemistry. 2001. V.46. N3. P.376-381. WOS Scopus РИНЦ
Reaction of Polynuclear Platinum Carbonyl with Tin(II) Chloride
Russian Journal of Inorganic Chemistry. 2001. V.46. N3. P.376-381. WOS Scopus РИНЦ
Original:
Шитова Н.Б.
, Перфильев Ю.Д.
, Альт Л.Я.
, Савельева Г.Г.
Взаимодействие полиядерного карбонила платины с хлоридом двухвалентного олова
Журнал неорганической химии. 2001. Т.46. №3. С.438-443. Scopus РИНЦ ANCAN
Взаимодействие полиядерного карбонила платины с хлоридом двухвалентного олова
Журнал неорганической химии. 2001. Т.46. №3. С.438-443. Scopus РИНЦ ANCAN
Dates:
| Submitted: | Mar 30, 2000 |
| Published print: | Mar 1, 2001 |
Identifiers:
| Web of science: | WOS:000167513800012 |
| Scopus: | 2-s2.0-0042411215 |
| Elibrary: | 13371853 |