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Broadband Dielectric Properties of Onion-Like Carbon/Polyurethane Composites Научная публикация

Журнал Physica Status Solidi (A) Applications and Materials (after 2004)
ISSN: 1862-6300 , E-ISSN: 1862-6319
Вых. Данные Год: 2013, Том: 210, Номер: 12, Страницы: 2683-2688 Страниц : 6 DOI: 10.1002/pssa.201330257
Ключевые слова PERCOLATION-THRESHOLD; RELAXATION
Авторы Macutkevic Jan 1 , Banys Juras 1 , Kuznetsov Vladimir 2 , Moseenkov Sergei 2 , Shenderova Olga 3
Организации
1 University of Vilnius, Sauletekio al. 9, 00122 Vilnius, Lithuania
2 Boreskov Institute of Catalysis SB RAS, Lavrentiev Ave. 5, 630090 Novosibirsk, Russia
3 International Technology Center, Raleigh, NC 27715, USA

Информация о финансировании (1)

1 European Commission

Реферат: The results of an investigation of the broadband dielectric properties of onion-like carbon (OLC)/polyurethane (PU) composites over a wide temperature range (300–450 K) are presented. The onset of the percolation threshold reached at 10 vol% of OLC is accompanied by drastically increased microwave absorption. The broadband dielectric properties of the composites at low loading of OLC, below the percolation threshold, are mainly governed by the α relaxation, the dynamics of the “soft” molecular segment of the PU chain. With increased OLC concentration, the glass-transition temperature decreases and the α relaxation completely vanishes for the composite with 5 vol% OLC. As the α relaxation vanishes rapid enhancement of the mobility of the soft molecular segments in PU chains occurs and a decrease of the activation energy of electrical conductivity follows.Keywords: composites; dielectric properties; onion-like carbon
Библиографическая ссылка: Macutkevic J. , Banys J. , Kuznetsov V. , Moseenkov S. , Shenderova O.
Broadband Dielectric Properties of Onion-Like Carbon/Polyurethane Composites
Physica Status Solidi (A) Applications and Materials (after 2004). 2013. V.210. N12. P.2683-2688. DOI: 10.1002/pssa.201330257 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 28 авг. 2013 г.
Принята к публикации: 11 сент. 2013 г.
Опубликована online: 4 окт. 2013 г.
Опубликована в печати: 1 дек. 2013 г.
Идентификаторы БД:
Web of science: WOS:000328452500024
Scopus: 2-s2.0-84890432466
РИНЦ: 21466465
Chemical Abstracts: 2013:1608009
Chemical Abstracts (print): 160:496280
OpenAlex: W1585319542
Цитирование в БД:
БД Цитирований
Web of science 6
Scopus 6
РИНЦ 6
OpenAlex 6
Альметрики: