Reaction of Substituted 5-Bromoacenaphthenes with the Catalytic Reduction System NiCl2-2,2'-Bipyridyl (or 1,10-Phenanthroline)-Zn | Sciact - CRIS-system of Boreskov Institute of Catalysis

Reaction of Substituted 5-Bromoacenaphthenes with the Catalytic Reduction System NiCl2-2,2'-Bipyridyl (or 1,10-Phenanthroline)-Zn Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Output data

Year: 1999, Volume: 35, Number: 6, Pages: 913-915 Pages count : 3

Authors

Adonin N.Y. ¹ , Ryabinin V.A. ¹ , Starichenko V.F. ¹

Affiliations

1	Novosibirsk Institute of Organic Chemistry, Russian Academy of Sciences, Novosibirsk

Transformations of substituted 5-bromoacenaphthenes under the action of a catalytic reduction system NiCl2-2,2'-bipyridyl (or 1,10-phenanthrolyne)-Zn in DMF and DMA was studied. Two types of transformation are shown to be characteristic for the studied compounds: reductive coupling with formation of the corresponding 5,5'-biacenaphthenyl and halogen elimination with hydrogen replacing the halogen. Yields of the coupling products and that of dehalogenation are found to depend substantially on the nature of the substituents in the naphthalene ring.

Adonin N.Y. , Ryabinin V.A. , Starichenko V.F.
Reaction of Substituted 5-Bromoacenaphthenes with the Catalytic Reduction System NiCl2-2,2'-Bipyridyl (or 1,10-Phenanthroline)-Zn
Russian Journal of Organic Chemistry. 1999. V.35. N6. P.913-915. Scopus РИНЦ ANCAN

Адонин Н.Ю. , Рябинин В.А. , Стариченко В.Ф.
Взаимодействие замещенных 5-бромаценафтенов с каталитической восстановительной системой NiCl2 - 2,2'-бипиридил (или 1,10-фенантролин) - Zn
Журнал органической химии. 1999. Т.35. №6. С.938-940. WOS

Published print:

Jun 1, 1999

Scopus:	2-s2.0-0033243421
Elibrary:	13331187
Chemical Abstracts:	1999:745237
Chemical Abstracts (print):	132:93090

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