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Rearrangements of Some Sesquiterpenes of the Aromadendrane and Guaiane Series in Acidic Media Full article

Journal Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393
Output data Year: 2000, Volume: 36, Number: 1, Pages: 40-54 Pages count : 15
Authors Polovinka M.P. 1 , Shalʹko A.A. 1 , Korchagina D.V. 1 , Gatilov Y.V. 1 , Shcherbukhin V.V. 1 , Zenkovets G.A. 2 , Barkhash V.A. 1
Affiliations
1 Novosibirsk Inst. of Organ. C., Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent'eva 9, Novosibirsk, 630090, Russian Federation
2 Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent'eva 5, Novosibirsk, 630090, Russian Federation

Abstract: (+)-Ledene and (+)-aromadendrene undergo rearrangements in various acidic media (HSO3F-SO2FCl, HCOOH, and over TiO2/SO2- 4) to give new tricyclic and spirocyclic compounds. Under the same conditions structurally related (-)-isoledene and (+)-γ-gurjunene give rise to mixtures of bicyclic dienes having a guaiane skeleton. The experimental data are discussed with regard to the results of computer simulation of the most favorable transformation pathways by molecular-mechanics and quantum-chemical methods.
Cite: Polovinka M.P. , Shalʹko A.A. , Korchagina D.V. , Gatilov Y.V. , Shcherbukhin V.V. , Zenkovets G.A. , Barkhash V.A.
Rearrangements of Some Sesquiterpenes of the Aromadendrane and Guaiane Series in Acidic Media
Russian Journal of Organic Chemistry. 2000. V.36. N1. P.40-54. Scopus РИНЦ ANCAN
Original: Половинка М.П. , Шалько А.А. , Корчагина Д.В. , Гатилов Ю.В. , Щербухин В.В. , Зенковец Г.А. , Бархаш В.А.
Перегруппировки некоторых сесквитерпенов аромдендранового и гвайанового рядов в различных кислотных средах
Журнал органической химии. 2000. Т.36. №1. С.49-61. WOS РИНЦ
Dates:
Published print: Jan 1, 2000
Identifiers:
Scopus: 2-s2.0-0033633718
Elibrary: 13346695
Chemical Abstracts: 2000:458630
Chemical Abstracts (print): 133:238135
Citing:
DB Citing
Scopus 5
Elibrary 12