Biomimetic Oxidation on Fe Complexes in Zeolites Full article
| Conference |
11th International Congress on Catalysis - 40th Anniversary 30 Jun - 5 Jul 1996 , Baltimore |
||
|---|---|---|---|
| Source | 11th International Congress on Catalysis - 40th Anniversary : Proceedings of the 11th ICC, 30 June-5 July 1996, Baltimore, MD, USA Compilation, 1996. 1441 c. ISBN 9780444819475. |
||
| Journal |
Studies in Surface Science and Catalysis
ISSN: 0167-2991 |
||
| Output data | Year: 1996, Volume: 101 A, Pages: 493-502 Pages count : 10 DOI: 10.1016/S0167-2991(96)80260-6 | ||
| Tags | N2O DECOMPOSITION; ZSM-5 ZEOLITE; OXO PROTEINS; IRON; HYDROXYLATION; BENZENE; MODELS; CYTOCHROME-P-450; MOSSBAUER; CENTERS | ||
| Authors |
|
||
| Affiliations |
|
Abstract:
One-step hydroxylation of aromatic nucleus with nitrous oxide (N20) is among recently discovered organic reactions. A high efficiency of FeZSM-5 zeolites in this reaction relates to a pronounced biomimetic-type activity of iron complexes stabilized in ZSM-5 matrix. N20 decomposition on these complexes produces particular atomic oxygen form (a-oxygen), whose chemistry is similar to that performed by the active oxygen of enzyme monooxygenases. Room temperature oxidation reactions of a-oxygen as well as the data on the kinetic isotope effect and Moessbauer spectroscopy show FeZSM-5 zeolite to be a successful biomimetic model.
Cite:
Panov G.I.
, Sobolev V.I.
, Dubkov K.A.
, Kharitonov A.S.
Biomimetic Oxidation on Fe Complexes in Zeolites
In compilation 11th International Congress on Catalysis - 40th Anniversary : Proceedings of the 11th ICC, 30 June-5 July 1996, Baltimore, MD, USA. 1996. – C.493-502. – ISBN 9780444819475. DOI: 10.1016/S0167-2991(96)80260-6 WOS Scopus РИНЦ ANCAN OpenAlex
Biomimetic Oxidation on Fe Complexes in Zeolites
In compilation 11th International Congress on Catalysis - 40th Anniversary : Proceedings of the 11th ICC, 30 June-5 July 1996, Baltimore, MD, USA. 1996. – C.493-502. – ISBN 9780444819475. DOI: 10.1016/S0167-2991(96)80260-6 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Published print: | Jan 1, 1996 |
| Published online: | Sep 2, 2007 |
Identifiers:
| Web of science: | WOS:A1996BG17S00051 |
| Scopus: | 2-s2.0-2242477558 |
| Elibrary: | 15055462 |
| Chemical Abstracts: | 1996:611404 |
| Chemical Abstracts (print): | 125:268751 |
| OpenAlex: | W1513841249 |