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Catalysts for Hydrogen Production in a Multifuel Processor by Methanol, Dimethyl Ether and Bioethanol Steam Reforming for Fuel Cell Applications Научная публикация

Журнал International Journal of Hydrogen Energy
ISSN: 0360-3199 , E-ISSN: 1879-3487
Вых. Данные Год: 2012, Том: 37, Номер: 21, Страницы: 16388-16396 Страниц : 9 DOI: 10.1016/j.ijhydene.2012.02.116
Ключевые слова Bioethanol, Dimethyl ether, Methanol, opper-cerium oxide, Steam reforming
Авторы Snytnikov P.V. 1,2,3 , Badmaev S.D. 1,2,3 , Volkova G.G. 1 , Potemkin D.I. 1,2,3 , Zyryanova M.M. 1,2,3 , Belyaev V.D. 1,2,3 , Sobyanin V.A. 1,2
Организации
1 Boreskov Institute of Catalysis, Pr. Akademika Lavrentieva 5, Novosibirsk 630090, Russia
2 Novosibirsk State University, Pirogova St. 2, Novosibirsk 630090, Russia
3 ”UNICAT” Ltd., Pr. Akademika Lavrentieva 5, Novosibirsk 630090, Russia

Информация о финансировании (2)

1 Министерство образования и науки Российской Федерации 16.516.11.6006
2 Министерство образования и науки Российской Федерации П960

Реферат: Methanol, dimethyl ether and bioethanol steam reforming to hydrogen-rich gas were studied over CuO/CeO2 and CuO-CeO2/gamma-Al2O3 catalysts. Both catalysts were found to provide complete conversion of methanol to hydrogen-rich gas at 300-350 degrees C. Complete conversion of dimethyl ether to hydrogen-rich gas occurred over CuO CeO2/gamma-Al2O3 at 350-370 degrees C. Complete conversion of ethanol to hydrogen-rich gas occurred over CuO/CeO2 at 350 degrees C. In both cases, the CO content in the obtained gas mixture was low (<2 vol.%). This hydrogen-rich gas can be used directly for fuelling high-temperature PEM FC. For fuelling low-temperature PEM FC, it is needed only to clean up the hydrogen-rich gas from CO to the level of 10 ppm. CuO/CeO2 catalyst can be used for this purpose as well. Since no individual WGS stage, that is necessary in most other hydrogen production processes, is involved here, the miniaturization of the multifuel processor for hydrogen production by methanol, ethanol or DME SR is quite feasible
Библиографическая ссылка: Snytnikov P.V. , Badmaev S.D. , Volkova G.G. , Potemkin D.I. , Zyryanova M.M. , Belyaev V.D. , Sobyanin V.A.
Catalysts for Hydrogen Production in a Multifuel Processor by Methanol, Dimethyl Ether and Bioethanol Steam Reforming for Fuel Cell Applications
International Journal of Hydrogen Energy. 2012. V.37. N21. P.16388-16396. DOI: 10.1016/j.ijhydene.2012.02.116 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 15 нояб. 2011 г.
Принята к публикации: 20 февр. 2012 г.
Опубликована online: 20 мар. 2012 г.
Опубликована в печати: 1 нояб. 2012 г.
Идентификаторы БД:
Web of science: WOS:000311196800057
Scopus: 2-s2.0-84867395996
РИНЦ: 22069757
Chemical Abstracts: 2012:425031
Chemical Abstracts (print): 159:152403
OpenAlex: W1976103390
Цитирование в БД:
БД Цитирований
Web of science 42
Scopus 46
РИНЦ 41
OpenAlex 50
Альметрики: