Cu, Co, Ag-Containing Pillared Clays as Catalysts for the Selective Reduction of NOx by Hydrocarbons in an Excess of Oxygen | Sciact - CRIS-system of Boreskov Institute of Catalysis

Cu, Co, Ag-Containing Pillared Clays as Catalysts for the Selective Reduction of NOx by Hydrocarbons in an Excess of Oxygen Full article

Conference

5th Congress on Catalysis and Automotive Pollution Control
12-14 Apr 2000 , Brussels

Journal

Topics in Catalysis
ISSN: 1022-5528 , E-ISSN: 1572-9028

Output data

Year: 2001, Volume: 16-17, Number: 1-4, Pages: 193-197 Pages count : 5 DOI: 10.1023/A:1016667822516

Tags

Catalysis, Clay, DRIFT, ESR, FTIR, Nitrogen oxides, NOx, PILC, SCR, TPD, TPR, Zirconia, ZrO2

Authors

Konin G.A. ¹ , Il'ichev A.N. ¹ , Matyshak V.A. ¹ , Khomenko T.I. ¹ , Korchak V.N. ¹ , Sadykov V.A. ² , Doronin V.P. ² , Bunina R.V. ² , Alikina G.M. ² , Kuznetsova T.G. ² , Paukshtis E.A. ² , Fenelonov V.B. ² , Zaikovskii V.I. ² , Ivanova A.S. ² , Beloshapkin S.A. ² , Rozovskii A.Ya. ³ , Tretyakov V.F. ³ , Ross J.R.H. ⁴ , Breen J.P. ⁴

Affiliations

1	Semenov Institute of Chemical Physics RAS, Kosygina st., 4, Moscow 117334, Russia
2	Boreskov Institute of Catalysis SB RAS, Lavrentieva, 5, Novosibirsk 630090, Russia
3	Topchiev Institute of Petrochemical Synthesis RAS, Leninskii pr., 29, Moscow, Russia
4	University of Limerick, Plassey Technological Park, Limerick, Ireland

Funding (2)

1	International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union	97-1730
2	Haldor Topsoe A/S

Thermally stable Al- and Zr-PILC loaded with copper and cobalt cations and silver nanoparticles were synthesized. The structural and surface features of these nanosystems were studied and compared with those of bulk analogs – partially stabilized ZrO2 loaded with the same active components. Specificity of the catalytic properties of nanocomposites in SCR of NOx by propane, propylene and decane in the excess of oxygen appears to be determined both by distribution of active components on the catalytic surface and degree of their interaction with supports. Formation of ads.-NOx, nitroxyl-hydrocarbon CxHyNO2⋅ and isocyanate NCO intermediates was observed by ESR and IR spectroscopy in situ.

Konin G.A. , Il'ichev A.N. , Matyshak V.A. , Khomenko T.I. , Korchak V.N. , Sadykov V.A. , Doronin V.P. , Bunina R.V. , Alikina G.M. , Kuznetsova T.G. , Paukshtis E.A. , Fenelonov V.B. , Zaikovskii V.I. , Ivanova A.S. , Beloshapkin S.A. , Rozovskii A.Y. , Tretyakov V.F. , Ross J.R.H. , Breen J.P.
Cu, Co, Ag-Containing Pillared Clays as Catalysts for the Selective Reduction of NOx by Hydrocarbons in an Excess of Oxygen
Topics in Catalysis. 2001. V.16-17. N1-4. P.193-197. DOI: 10.1023/A:1016667822516 WOS Scopus РИНЦ ANCAN OpenAlex

Published print:

Sep 1, 2001

Web of science:	WOS:000171632100029
Scopus:	2-s2.0-0037576122
Elibrary:	13369948
Chemical Abstracts:	2001:765342
Chemical Abstracts (print):	136:122514
OpenAlex:	W309132810

DB	Citing
Web of science	29
Scopus	35
Elibrary	38
OpenAlex	30