Reactions of Rhodium (II) Acetate with Non-Lacunary Keggin and Dawson Polyoxoanions and Related Catalytic Studies | Sciact - CRIS-system of Boreskov Institute of Catalysis

Reactions of Rhodium (II) Acetate with Non-Lacunary Keggin and Dawson Polyoxoanions and Related Catalytic Studies Full article

Journal

Inorganica Chimica Acta
ISSN: 0020-1693 , E-ISSN: 1873-3255

Output data

Year: 2013, Volume: 394, Pages: 656-662 Pages count : 7 DOI: 10.1016/j.ica.2012.07.028

Tags

Crystal structures, Dawson structure, Keggin structure, Polyoxometalates, Rhodium

Authors

Sokolov Maxim N. ^1,2 , Adonin Sergey A. ^1,2 , Peresypkina Eugenia V. ¹ , Abramov Pavel A. ^1,2 , Smolentsev Anton I. ¹ , Potemkin Dmitry I. ^2,3 , Snytnikov Pavel V. ^2,3 , Fedin Vladimir P. ^1,2

Affiliations

1	Nikolayev Institute of Inorganic Chemistry, Prospekt Lavrentyeva 3, 630090 Novosibirsk, Russia
2	Novosibirsk State University, Faculty of Natural Sciences, Pirogova St. 2, 630090 Novosibirsk, Russia
3	Boreskov Institute of Catalysis SB RAS, Prospekt Lavrentyeva 5, 630090 Novosibirsk, Russia

Funding (4)

1	Russian Foundation for Basic Research	09-03-93105
2	Haldor Topsoe A/S
3	The Ministry of Education and Science of the Russian Federation	11.519.11.3021
4	The Ministry of Education and Science of the Russian Federation	14.740.11.0273

Reactions of non-lacunary Keggin ([PW12O40]3−) and Dawson ([α-P2W18O62]6−) polyoxometalates with rhodium (II) acetate have been studied. In the first case reaction yields the layered coordination polymer Li3[(Rh2(CH3COO)4)2(PW12O40)]·12.5 H2O (1), where polyoxoanions are coordinated via oxygen atoms to the {Rh2}4+ core. In the case of [α-P2W18O62]6− dirhodium clusters do not coordinate the polyoxoanion directly; however, they form K7[P2W18O62][Rh2(CH3COO)4X]·nH2O, where X = Cl, n = 11.37 (2); Br, n = 11.1 (3), which contain polymeric chain polyanions catena-[Rh2(CH3COO)4X]nn− (X = Cl, Br). Coordination polymer 1 is active in total oxidation of hydrogen and olefin at relatively low temperatures.

Sokolov M.N. , Adonin S.A. , Peresypkina E.V. , Abramov P.A. , Smolentsev A.I. , Potemkin D.I. , Snytnikov P.V. , Fedin V.P.
Reactions of Rhodium (II) Acetate with Non-Lacunary Keggin and Dawson Polyoxoanions and Related Catalytic Studies
Inorganica Chimica Acta. 2013. V.394. P.656-662. DOI: 10.1016/j.ica.2012.07.028 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Apr 2, 2012
Accepted:	Jul 25, 2012
Published online:	Aug 17, 2012
Published print:	Jan 1, 2013

Web of science:	WOS:000311492900087
Scopus:	2-s2.0-84870245606
Elibrary:	20416059
Chemical Abstracts:	2012:1600077
Chemical Abstracts (print):	158:64798
OpenAlex:	W2022914607

DB	Citing
Web of science	18
Scopus	19
Elibrary	18
OpenAlex	19