[Pd(NH3)4]MoO4 as a Precursor for Pd–Mo-Containing Catalysts: Thermal Behavior, X-Ray Analysis of the Thermolysis Products and Related Catalytic Studies | Sciact - CRIS-system of Boreskov Institute of Catalysis

[Pd(NH3)4]MoO4 as a Precursor for Pd–Mo-Containing Catalysts: Thermal Behavior, X-Ray Analysis of the Thermolysis Products and Related Catalytic Studies Full article

Journal

Thermochimica Acta
ISSN: 0040-6031 , E-ISSN: 1872-762X

Output data

Year: 2013, Volume: 566, Pages: 100-104 Pages count : 5 DOI: 10.1016/j.tca.2013.03.036

Tags

Catalysis, Pd-Mo nanoalloy, Tetraamminepalladium(II) molybdate, Thermal behavior

Authors

Gubanov Alexander I. ^1,2 , Filatov Eugeny Yu. ^1,2 , Semitut Eugeny Yu. ^1,2 , Smolentsev Anton I. ^1,2 , Snytnikov Pavel V. ^2,3 , Potemkin Dmitry I. ^2,3 , Korenev Sergey V. ^1,2

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Akad. Lavrentiev Prospekt 3, 630090 Novosibirsk, Russian Federation
2	Novosibirsk State University, Pirogova str. 2, 630090 Novosibirsk, Russian Federation
3	Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Akad. Lavrentiev Prospekt 5, 630090 Novosibirsk, Russian Federation

Funding (4)

1	Russian Foundation for Basic Research	11-03-00168
2	Siberian Branch of the Russian Academy of Sciences	64
3	The Ministry of Education and Science of the Russian Federation	11.519.11.3021
4	Council for Grants of the President of the Russian Federation	СП-857.2012.1

Compound [Pd(NH3)4]MoO4 (1) has been synthesized and characterized by IR spectroscopy, analytical data, powder and single-crystal X-ray crystallography. Thermal properties of 1 have been examined by thermogravimetry. Powder X-ray diffraction has been applied to investigate the nanosized products of thermal decomposition of the precursor in hydrogen (Pd–Mo) and helium (Pd–MoO2) atmospheres. Pd–Mo catalysts supported with γ-Al2O3 have been tested in oxidation of CO and H2 mixtures.

Gubanov A.I. , Filatov E.Y. , Semitut E.Y. , Smolentsev A.I. , Snytnikov P.V. , Potemkin D.I. , Korenev S.V.
[Pd(NH3)4]MoO4 as a Precursor for Pd–Mo-Containing Catalysts: Thermal Behavior, X-Ray Analysis of the Thermolysis Products and Related Catalytic Studies
Thermochimica Acta. 2013. V.566. P.100-104. DOI: 10.1016/j.tca.2013.03.036 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Dec 11, 2012
Accepted:	Mar 22, 2013
Published online:	May 4, 2013
Published print:	Aug 20, 2013

Web of science:	WOS:000322685700014
Scopus:	2-s2.0-84884522376
Elibrary:	20456995
Chemical Abstracts:	2013:1142543
Chemical Abstracts (print):	161:47163
OpenAlex:	W2023849379

DB	Citing
Web of science	11
Scopus	11
Elibrary	15
OpenAlex	17