Synthesis and Characterisation of Co–Mo Complexes Containing the [Co(C2H8N2)3]2+ Cation and [Mo2O7L]4− Anion, where L is an Oxalic, Tartaric, Citric or Nitrilotriacetic Acid Residue Научная публикация
| Журнал |
Polyhedron
ISSN: 0277-5387 |
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| Вых. Данные | Год: 2012, Том: 47, Номер: 1, Страницы: 65-72 Страниц : 8 DOI: 10.1016/j.poly.2012.08.025 | ||
| Ключевые слова | Citrate, Cobalt, Molybdenum, NTA, Oxalate, Tartrate | ||
| Авторы |
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| Организации |
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Информация о финансировании (1)
| 1 | Министерство образования и науки Российской Федерации | 16.518.11.7019 |
Реферат:
A set of bimetallic Co–Mo complexes has been synthesised in yields of approximately 95% by the sequential dissolution of ethylenediamine, different Co2+ carboxylates and ammonium heptamolybdate in water. Data collected from elemental analysis, XRD, UV–Vis, IR, Raman, XPS, and EXAFS spectroscopy suggest that all of the complexes have similar structures that correspond to the general formula of NH4(enH2)x[Co(en)3][Mo2O7L]·H2O, where L is oxalic, tartaric, citric or nitrilotriacetic acid residue. A special feature of the complexes is the presence of two different molybdenum atoms linked together by an oxygen bridge in an octahedral and tetrahedral oxygen environment, as well as a cobalt 2+ atom that is in an octahedral environment with the nitrogen atoms of the ethylenediamine.
Библиографическая ссылка:
Leonova K.A.
, Klimov O.V.
, Kochubey D.I.
, Chesalov Y.A.
, Prosvirin I.P.
, Larina T.V.
, Noskov A.S.
Synthesis and Characterisation of Co–Mo Complexes Containing the [Co(C2H8N2)3]2+ Cation and [Mo2O7L]4− Anion, where L is an Oxalic, Tartaric, Citric or Nitrilotriacetic Acid Residue
Polyhedron. 2012. V.47. N1. P.65-72. DOI: 10.1016/j.poly.2012.08.025 WOS Scopus РИНЦ CAPlusCA OpenAlex
Synthesis and Characterisation of Co–Mo Complexes Containing the [Co(C2H8N2)3]2+ Cation and [Mo2O7L]4− Anion, where L is an Oxalic, Tartaric, Citric or Nitrilotriacetic Acid Residue
Polyhedron. 2012. V.47. N1. P.65-72. DOI: 10.1016/j.poly.2012.08.025 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Поступила в редакцию: | 25 мая 2012 г. |
| Принята к публикации: | 8 авг. 2012 г. |
| Опубликована online: | 24 авг. 2012 г. |
| Опубликована в печати: | 1 окт. 2012 г. |
Идентификаторы БД:
| Web of science: | WOS:000311179800010 |
| Scopus: | 2-s2.0-84866282865 |
| РИНЦ: | 20481284 |
| Chemical Abstracts: | 2012:1544276 |
| Chemical Abstracts (print): | 157:751782 |
| OpenAlex: | W2011271380 |