Promoted Iron Catalysts of Low-Temperature Methane Decomposition | Sciact - CRIS-system of Boreskov Institute of Catalysis

Promoted Iron Catalysts of Low-Temperature Methane Decomposition Full article

Conference

Catalysis for sustainable development : Russian-Dutch Workshop
22-26 Jun 2002 , Novosibirsk, Russia

Journal

Химия в интересах устойчивого развития
ISSN: 0869-8538

Output data

Year: 2003, Volume: 11, Number: 1, Pages: 239-248 Pages count : 9

Authors

Reshetenko T.V. ¹ , Avdeeva L.B. ¹ , Ismagilov Z.R. ¹ , Ushakov V.A. ¹ , Chuvilin A.L. ¹ , Pavlyukhin Yu.T. ²

Affiliations

1	G. K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Pr. Akademika Lavrentyeva 5, Novosibirsk 630090
2	Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch of the Russian Academy of Sciences, Ul. Kutateladze 18, Novosibirsk 630128 (Russia)

Funding (2)

1	Civilian Research and Development Foundation	REC-008
2	Netherlands Organisation for Scientific Research	NWO-2001

Iron-containing catalysts promoted by nickel or cobalt were tested in methane decomposition reaction at low temperature (600–650 °C) and pressure 1 bar in order to study their catalytic properties and to produce catalytic filamentous carbon (CFC). Catalyst preparation method and composition of the catalysts were found to influence their properties. It was found, that introduction of cobalt or nickel in small amount (3–10 % mass) results in the magnification of carbon yields 2–3 times in comparison with Fe-Al2O3. Investigations of Fe-Co-Al2O3 and Fe-Ni-Al2O3 catalysts genesis were performed by Mössbauer spectroscopy, XRD, TEM. It is established that Co or Ni additives render activating influence on Fe catalysts which become apparent in decrease of the methane decomposition temperature and the formation of multiwall carbon nanotubes (MWNTs).

Reshetenko T.V. , Avdeeva L.B. , Ismagilov Z.R. , Ushakov V.A. , Chuvilin A.L. , Pavlyukhin Y.T.
Promoted Iron Catalysts of Low-Temperature Methane Decomposition
Химия в интересах устойчивого развития. 2003. V.11. N1. P.239-248. РИНЦ ANCAN

Reshetenko T.V. , Avdeeva L.B. , Ismagilov Z.R. , Ushakov V.A. , Chuvilin A.L. , Pavlyukhin Y.T.
Promoted Iron Catalysts of Low-Temperature Methane Decomposition
Chemistry for Sustainable Development. 2003. V.11. N1. P.239-247. РИНЦ

Elibrary:	17749441
Chemical Abstracts:	2003:278873
Chemical Abstracts (print):	139:38753

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