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On the Mechanism of Olefin Polymerization by Ziegler-Natta Catalysts Review

Source Industrial Developments
Compilation, Springer. Berlin, Heidelberg.1983. 228 c. ISBN 9783540121893. ANCAN
Journal Advances in Polymer Science
ISSN: 0065-3195
Output data Year: 1983, Volume: 51, Pages: 61-100 Pages count : 40 DOI: 10.1007/BFb0017585
Authors Zakharov Vladimir A. 1 , Bukatov Gennadii D. 1 , Yermakov Yurii I. 1
Affiliations
1 Institute of Catalysis, Siberian Branch of the USSR Academy of Sciences, Novosibirsk 630090, USSR

Abstract: Novel data on the composition of active centers of Ziegler-Natta catalysts and on the mechanism of propagation and chain transfer reactions are reviewed. These data are derived from the following trends in the study of the mechanism of catalytic polymerization: a) determination of the number of active centers (mainly with the use of radioactive CO as a tag); b) analysis of the microstructure of polymers with the use of 13C-NMR; c) analysis of specific features of highly active supported catalysts; d) quantum-chemical calculation of the electronic structure of active centers and their reactions.
Cite: Zakharov V.A. , Bukatov G.D. , Yermakov Y.I.
On the Mechanism of Olefin Polymerization by Ziegler-Natta Catalysts
In compilation Industrial Developments. – Springer., 1983. – C.61-100. – ISBN 9783540121893. DOI: 10.1007/BFb0017585 WOS РИНЦ ANCAN OpenAlex
Dates:
Submitted: Oct 1, 1982
Published online: Jun 10, 2005
Identifiers:
Web of science: WOS:A1983RG15600002
Elibrary: 22693442
Chemical Abstracts: 1983:576290
Chemical Abstracts (print): 99:176290
OpenAlex: W149080949
Citing:
DB Citing
Web of science 42
Elibrary 62
OpenAlex 44
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