Effect of Substitution of Monoester by Diester on Titanium-Magnesium Catalyst Properties in Propene Polymerization Full article
| Journal |
Angewandte Makromolekulare Chemie
ISSN: 0003-3146 , E-ISSN: 1522-9505 |
||||
|---|---|---|---|---|---|
| Output data | Year: 1995, Volume: 231, Pages: 61-67 Pages count : 7 DOI: 10.1002/apmc.1995.052310106 | ||||
| Tags | ZIEGLER-NATTA CATALYSTS; KINETICS; DONORS; BASE | ||||
| Authors |
|
||||
| Affiliations |
|
Abstract:
Titanium-magnesium catalysts (TMC), containing monoester (ethyl benzoate) as internal donor, can be transferred to the diester TMC by the treatment with TiCl4 and dibutyl phthalate. The activity and the stereospecificity of the transferred TMC in propylene polymerization are close to those of TMC prepared directly in the presence of diester. The surface area and the porous structure of both types of TMC were studied and the correlation with the activity of these catalysts is discussed.
Cite:
Talapatra S.
, Dudchenko V.K.
, Bukatov G.D.
, Zakharov V.A.
, Okkel L.C.
Effect of Substitution of Monoester by Diester on Titanium-Magnesium Catalyst Properties in Propene Polymerization
Angewandte Makromolekulare Chemie. 1995. V.231. P.61-67. DOI: 10.1002/apmc.1995.052310106 WOS Scopus РИНЦ OpenAlex ANCAN
Effect of Substitution of Monoester by Diester on Titanium-Magnesium Catalyst Properties in Propene Polymerization
Angewandte Makromolekulare Chemie. 1995. V.231. P.61-67. DOI: 10.1002/apmc.1995.052310106 WOS Scopus РИНЦ OpenAlex ANCAN
Dates:
| Submitted: | Nov 14, 1994 |
| Published print: | Sep 1, 1995 |
| Published online: | Mar 12, 2003 |
Identifiers:
| ≡ Web of science: | WOS:A1995TB00500006 |
| ≡ Scopus: | 2-s2.0-0042593158 |
| ≡ Elibrary: | 31091190 |
| ≡ OpenAlex: | W1834745539 |
| ≡ Chemical Abstracts: | 1995:909255 |
| ≡ Chemical Abstracts (print): | 124:118059 |