Kinetic Model for the Reaction of Sulphur Dioxide Catalytic Reduction to Hydrogen Sulphide Full article
| Journal |
Applied Catalysis A: General
ISSN: 0926-860X , E-ISSN: 1873-3875 |
||
|---|---|---|---|
| Output data | Year: 1993, Volume: 101, Number: 1, Pages: 25-39 Pages count : 15 DOI: 10.1016/0926-860X(93)80135-D | ||
| Tags | catalytic reduction, kinetic model, methane oxidation, rate constants, statistical analysis, sulphurdioxide, thermodynamic analysis | ||
| Authors |
|
||
| Affiliations |
|
Abstract:
Kinetics for the complete catalytic reduction of sulphur dioxide by methane in the presence of an activated Al2O3 catalyst have been studied. Experiments were carried out in the flow laboratory reactor with the use of gas mixtures that model the composition of “strong” metallurgical gases containing 8–9 vol.-% oxygen and 12–15 vol.-% sulphur dioxide. Experimental data made it possible to ascertain the most probable chemical reactions which proceed in the above system within the temperature range 650–850 °C. The thermodynamic analysis results are given. A kinetic model is formulated. By solving the model identification problem the values for rate constants and activation energies are found.
Cite:
Yermakova A.
, Anikeev V.I.
, Bobrin A.S.
Kinetic Model for the Reaction of Sulphur Dioxide Catalytic Reduction to Hydrogen Sulphide
Applied Catalysis A: General. 1993. V.101. N1. P.25-39. DOI: 10.1016/0926-860X(93)80135-D WOS Scopus РИНЦ ANCAN OpenAlex
Kinetic Model for the Reaction of Sulphur Dioxide Catalytic Reduction to Hydrogen Sulphide
Applied Catalysis A: General. 1993. V.101. N1. P.25-39. DOI: 10.1016/0926-860X(93)80135-D WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Aug 11, 1992 |
| Accepted: | Mar 23, 1993 |
| Published print: | Jul 26, 1993 |
| Published online: | Aug 22, 2001 |
Identifiers:
| Web of science: | WOS:A1993LP80000004 |
| Scopus: | 2-s2.0-0027627283 |
| Elibrary: | 31088402 |
| Chemical Abstracts: | 1993:611546 |
| Chemical Abstracts (print): | 119:211546 |
| OpenAlex: | W2044916239 |