Ferrisilicate Analogs of ZSM-5 Zeolite as Catalysts for One-Step Oxidation of Benzene to Phenol Full article
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Applied Catalysis A: General
ISSN: 0926-860X , E-ISSN: 1873-3875 |
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| Output data | Year: 1993, Volume: 98, Number: 1, Pages: 33-43 Pages count : 11 DOI: 10.1016/0926-860X(93)85023-I | ||
| Tags | acidity, benzene to phenol oxidation, FeZSM-5 zeolite, iron, mechanisms, nitrous oxide as oxidant, phenol, zeolites | ||
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Abstract:
The role of iron in the catalytic properties of ZSM-5 ferrisilicate analogs in the oxidation of benzene to phenol by dinitrogen monoxide has been studied within a wide range of iron concentrations (from 0.003 to 4.8 wt.-% Fe2O3). The samples of the Fe-Si system with optimal iron content, as well as previously studied Fe-Al-Si samples of the same zeolite structure, were found to be far superior to known catalysts. A reaction mechanism is suggested, where the active form of the surface oxygen produced by dinitrogen monoxide decomposition is of key importance. Zeolite acidity was tested and its role in the catalytic activity is discussed.
Cite:
Kharitonov A.S.
, Sheveleva G.A.
, Panov G.I.
, Sobolev V.I.
, Paukshtis Y.A.
, Romannikov V.N.
Ferrisilicate Analogs of ZSM-5 Zeolite as Catalysts for One-Step Oxidation of Benzene to Phenol
Applied Catalysis A: General. 1993. V.98. N1. P.33-43. DOI: 10.1016/0926-860X(93)85023-I WOS Scopus РИНЦ OpenAlex ANCAN
Ferrisilicate Analogs of ZSM-5 Zeolite as Catalysts for One-Step Oxidation of Benzene to Phenol
Applied Catalysis A: General. 1993. V.98. N1. P.33-43. DOI: 10.1016/0926-860X(93)85023-I WOS Scopus РИНЦ OpenAlex ANCAN
Dates:
| Submitted: | Aug 15, 1992 |
| Accepted: | Jan 15, 1993 |
| Published print: | May 6, 1993 |
| Published online: | Sep 18, 2001 |
Identifiers:
| ≡ Web of science: | WOS:A1993LB21900003 |
| ≡ Scopus: | 2-s2.0-0027910426 |
| ≡ Elibrary: | 31099072 |
| ≡ OpenAlex: | W1969502482 |
| ≡ Chemical Abstracts: | 1993:256953 |
| ≡ Chemical Abstracts (print): | 118:256953 |