Effect of Pd/C Dispersion on Its Catalytic Properties in Acetylene and Vinylacetylene Hydrogenation Full article
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Applied Catalysis (up to 1991)
ISSN: 0166-9834 |
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| Output data | Year: 1989, Volume: 54, Number: 1, Pages: 277-288 Pages count : 12 DOI: 10.1016/S0166-9834(00)82370-2 | ||
| Tags | Carbon--Activated; Catalysis; Catalysts--Supported | ||
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Abstract:
In reactions of the selective hydrogenation of acetylene and vinylacetylene, the specific catalytic activity (turnover number, TON) and selectivity of Pd obtained via reduction of C3H5PdC5H5 anchored on active carbon, within a particle-size range of 30–110Å, is roughly constant and close to the TON of Pd over oxide supports (SiO2, Al2O3). The binding energy of the Pd 3d5/2 level of a low-dispersed Pd does not depend significantly on its particle size and the nature of the support. The TON of Pd/C containing particles <30Å is several times lower than that of low-dispersed Pd.
Cite:
Ryndin Y.A.
, Stenin M.V.
, Boronin A.I.
, Bukhtiyarov V.I.
, Zaikovskii V.I.
Effect of Pd/C Dispersion on Its Catalytic Properties in Acetylene and Vinylacetylene Hydrogenation
Applied Catalysis (up to 1991). 1989. V.54. N1. P.277-288. DOI: 10.1016/S0166-9834(00)82370-2 WOS Scopus РИНЦ ANCAN OpenAlex
Effect of Pd/C Dispersion on Its Catalytic Properties in Acetylene and Vinylacetylene Hydrogenation
Applied Catalysis (up to 1991). 1989. V.54. N1. P.277-288. DOI: 10.1016/S0166-9834(00)82370-2 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Jan 9, 1989 |
| Accepted: | Jun 8, 1989 |
| Published print: | Sep 15, 1989 |
| Published online: | Oct 2, 2001 |
Identifiers:
| Web of science: | WOS:A1989CA89700005 |
| Scopus: | 2-s2.0-0024751506 |
| Elibrary: | 22694298 |
| Chemical Abstracts: | 1990:97875 |
| Chemical Abstracts (print): | 112:97875 |
| OpenAlex: | W1999018008 |