Palladium Catalysts on Carbon Supports 2. Description of the Adsorption Equilibria of Pd(II) in the H2PdCl4-HCl-Carbon Support System Full article
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Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171 |
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| Output data | Year: 1989, Volume: 38, Number: 9, Pages: 1792-1796 Pages count : 5 DOI: 10.1007/BF00957763 | ||
| Tags | Oxygen; Chloride; Active Carbon; Palladium; Support System | ||
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Abstract:
A method for the mathematical description of equilibria of complexing of H2PdCl4 with type A1 and A2 surface sites for the carbon supports “Sibunit”, PMÉ-800 carbon black, and PN active carbon was proposed. The apparent constants of formation of Pd(II) chloride complexes with these sites, K1 and K2, respectively, were calculated. It was shown that for nonoxide supports, constant K2, in contrast to K1, is strongly dependent on the type of support, while both constants increase with an increase in the concentration of chemisorbed oxygen for the oxidized samples.
Cite:
Simonov P.A.
, Chuvilin A.L.
, Likholobov V.A.
Palladium Catalysts on Carbon Supports 2. Description of the Adsorption Equilibria of Pd(II) in the H2PdCl4-HCl-Carbon Support System
Russian Chemical Bulletin. 1989. V.38. N9. P.1792-1796. DOI: 10.1007/BF00957763 WOS Scopus РИНЦ OpenAlex
Palladium Catalysts on Carbon Supports 2. Description of the Adsorption Equilibria of Pd(II) in the H2PdCl4-HCl-Carbon Support System
Russian Chemical Bulletin. 1989. V.38. N9. P.1792-1796. DOI: 10.1007/BF00957763 WOS Scopus РИНЦ OpenAlex
Original:
Симонов П.А.
, Чувилин А.Л.
, Лихолобов В.А.
Палладиевые катализаторы на углеродных носителях. Сообщение 2. Описание равновесий адсорбции Pd(II) в системе H2PdCl4-HCl-углеродный носитель
Известия Академии наук. Серия химическая. 1989. №9. С.1952-1956. РИНЦ ANCAN
Палладиевые катализаторы на углеродных носителях. Сообщение 2. Описание равновесий адсорбции Pd(II) в системе H2PdCl4-HCl-углеродный носитель
Известия Академии наук. Серия химическая. 1989. №9. С.1952-1956. РИНЦ ANCAN
Dates:
| Submitted: | Apr 21, 1988 |
| Published print: | Sep 1, 1989 |
Identifiers:
| Web of science: | WOS:A1989DH98000003 |
| Scopus: | 2-s2.0-34249972094 |
| Elibrary: | 30987132 |
| OpenAlex: | W1974609243 |