Change in Sign of Exchange Integral in Conformational Transition in Molecule of Stable Nitroxyl Diradical Full article
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Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171 |
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| Output data | Year: 1981, Volume: 30, Number: 9, Pages: 1660-1663 Pages count : 4 DOI: 10.1007/BF00949467 | ||||
| Tags | Palladium; Thermodynamic Parameter; Conformational Transition; Nitroxyl; Palladium Complex | ||||
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Abstract:
Conclusions
1. A change in sign of the exchange integral has been found in the conformational restructuring of a molecule of a diradical palladium complex.
2. The thermodynamic parameters δH and δS and the values of the exchange integral J1 and J2 in the individual conformations of the diradical have been determined.
3. The conformation that is stabilized at low temperatures has been established.
Cite:
Kokorin A.I.
, Shubin A.A.
, Parmon V.N.
Change in Sign of Exchange Integral in Conformational Transition in Molecule of Stable Nitroxyl Diradical
Russian Chemical Bulletin. 1981. V.30. N9. P.1660-1663. DOI: 10.1007/BF00949467 WOS Scopus РИНЦ OpenAlex
Change in Sign of Exchange Integral in Conformational Transition in Molecule of Stable Nitroxyl Diradical
Russian Chemical Bulletin. 1981. V.30. N9. P.1660-1663. DOI: 10.1007/BF00949467 WOS Scopus РИНЦ OpenAlex
Original:
Кокорин А.И.
, Шубин А.А.
, Пармон В.Н.
Изменение знака обменного интеграла при конформационном переходе в молекуле стабильного нитроксильного бирадикала
Известия Академии наук. Серия химическая. 1981. №9. С.2023-2028. РИНЦ ANCAN
Изменение знака обменного интеграла при конформационном переходе в молекуле стабильного нитроксильного бирадикала
Известия Академии наук. Серия химическая. 1981. №9. С.2023-2028. РИНЦ ANCAN
Dates:
| Submitted: | Dec 30, 1980 |
| Published print: | Sep 1, 1981 |
Identifiers:
| Web of science: | WOS:A1981NV67100017 |
| Scopus: | 2-s2.0-34250226165 |
| Elibrary: | 30906722 |
| OpenAlex: | W2006422585 |