Mechanism of Oxidation of Xylenes with Pd(II) Complexes Full article
| Journal |
Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171 |
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| Output data | Year: 1985, Volume: 34, Number: 10, Pages: 2001-2007 Pages count : 7 DOI: 10.1007/BF00963221 | ||
| Tags | Oxidation; Acidity; Palladium; Xylene; Acidic Medium | ||
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Abstract:
Conclusions
Oxidation of xylenes with Pd(II) complexes in acidic medium is possible according to two pathways: a) electrophilic substitution in the arene ring with the formation of an organometalic intermediate and b) one-electron transfer from the arene to the palladium atom with the intermediacy of the arene cation-radical. The relative contribution of each pathway depends on the nature of the arene and on the acidity of the medium.
Cite:
Kozhevnikov I.V.
, Kim V.I.
, Talsi E.P.
Mechanism of Oxidation of Xylenes with Pd(II) Complexes
Russian Chemical Bulletin. 1985. V.34. N10. P.2001-2007. DOI: 10.1007/BF00963221 WOS Scopus РИНЦ OpenAlex
Mechanism of Oxidation of Xylenes with Pd(II) Complexes
Russian Chemical Bulletin. 1985. V.34. N10. P.2001-2007. DOI: 10.1007/BF00963221 WOS Scopus РИНЦ OpenAlex
Original:
Кожевников И.В.
, Ким В.И.
, Талзи Е.П.
Механизм окисления ксилолов комплексами Pd (II)
Известия Академии наук. Серия химическая. 1985. №10. С.2167-2174. РИНЦ ANCAN
Механизм окисления ксилолов комплексами Pd (II)
Известия Академии наук. Серия химическая. 1985. №10. С.2167-2174. РИНЦ ANCAN
Dates:
| Submitted: | Jun 11, 1984 |
| Published print: | Oct 1, 1985 |
Identifiers:
| Web of science: | WOS:A1985C800800001 |
| Scopus: | 2-s2.0-34250115726 |
| Elibrary: | 30906324 |
| OpenAlex: | W1975032124 |