Hydrogen Isotope Exchange Catalyzed by Phosphine Complexes of Palladium | Sciact - CRIS-system of Boreskov Institute of Catalysis

Hydrogen Isotope Exchange Catalyzed by Phosphine Complexes of Palladium Full article

Journal

Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171

Output data

Year: 1985, Volume: 34, Number: 8, Pages: 1577-1581 Pages count : 5 DOI: 10.1007/BF00948495

Tags

Hydrogen; Ethylene; Aqueous Solution; Carbon Monoxide; Hydrogen Atom

Authors

Zudin V.N. ¹ , Rogov V.A. ¹ , Likholobov V.A. ¹ , Shmachkov V.A. ¹ , Sazonov L.A. ¹ , Ermakov Y.I. ¹

Affiliations

1	Institute of Catalysis, Siberian Branch, Academy of Sciences of the USSR

Conclusions 1. Bis(triphenylphosphine)bis(trifluoroacetato)palladium in aqueous solutions of trifluoroacetic acid catalyzes the isotope exchange of hydrogen between dihydrogen and the protons of the solvent. 2. Hydrogen exchange proceeds through the formation and decomposition of a hydride complex of palladium, the hydrogen atom in which is capable of exchanging with the protons of the solvent. 3. The introduction of ethylene into the system lowers the rate of the hydrogen exchange reaction, and the presence of a mixture of ethylene and carbon monoxide completely inhibits this reaction.

Zudin V.N. , Rogov V.A. , Likholobov V.A. , Shmachkov V.A. , Sazonov L.A. , Ermakov Y.I.
Hydrogen Isotope Exchange Catalyzed by Phosphine Complexes of Palladium
Russian Chemical Bulletin. 1985. V.34. N8. P.1577-1581. DOI: 10.1007/BF00948495 WOS Scopus РИНЦ OpenAlex

Зудин В.Н. , Рогов В.А. , Лихолобов В.А. , Шмачков В.А. , Сазонов Л.А. , Ермаков Ю.И.
Изучение изотопного обмена водорода, катализируемого фосфиновым комплексом палладия
Известия Академии наук. Серия химическая. 1985. №8. С.1726-1730. РИНЦ ANCAN

Submitted:	Apr 24, 1984
Published print:	Aug 1, 1985

Web of science:	WOS:A1985A385900006
Scopus:	2-s2.0-34250114990
Elibrary:	30836844
OpenAlex:	W2094962040

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