One-Pot myrtenol Amination over Au Nanoparticles Supported on Different Metal Oxides | Sciact - CRIS-system of Boreskov Institute of Catalysis

One-Pot myrtenol Amination over Au Nanoparticles Supported on Different Metal Oxides Full article

Journal

Applied Catalysis A: General
ISSN: 0926-860X , E-ISSN: 1873-3875

Output data

Year: 2013, Volume: 464-465, Pages: 348-356 Pages count : 9 DOI: 10.1016/j.apcata.2013.06.013

Tags

Amination, Gold nanoparticles, Myrtenol, One-pot

Authors

Demidova Yu.S. ¹ , Simakova I.L. ¹ , Estrada M. ² , Beloshapkin S. ³ , Suslov E.V. ⁴ , Korchagina D.V. ⁴ , Volcho K.P. ⁴ , Salakhutdinov N.F. ⁴ , Simakov A.V. ⁵ , Murzin D.Yu. ⁶

Affiliations

1	Boreskov Institute of Catalysis, pr. Lavrentieva, 5, 630090 Novosibirsk, Russia
2	Posgrado en Física de Materiales, CICESE, 22860 Ensenada, B.C., Mexico
3	Materials & Surface Science Institute, University of Limerick, Limerick, Ireland
4	Novosibirsk Institute of Organic Chemistry, pr. Lavrentieva, 9, 630090 Novosibirsk, Russia
5	Centro de Nanociencias y Nanotecnología, UNAM, 22860 Ensenada, B.C., Mexico
6	Process Chemistry Centre, Åbo Akademi University, FI-20500 Turku/Åbo, Finland

Funding (3)

1	National Autonomous University of Mexico National Council of Science and Technology	179619
2	National Autonomous University of Mexico	203813
3	Russian Foundation for Basic Research	12-03-31623

The one-pot amination of natural terpene alcohol (myrtenol, with a primary hydroxyl group) was studied over gold catalysts supported on different metal oxides such as ZrO2, MgO, Al2O3, CeO2, La2O3 using the equimolar amounts of substrates under nitrogen pressure. The synthesized catalysts were characterized by TEM, N2 adsorption techniques and XPS. The correlation between acid–base properties of support and catalytic performance was established. A nearly complete myrtenol conversion as well as the highest selectivity to secondary amine of about 52% were reached after 16 h over Au/ZrO2 with both acidic and basic surface sites.

Demidova Y.S. , Simakova I.L. , Estrada M. , Beloshapkin S. , Suslov E.V. , Korchagina D.V. , Volcho K.P. , Salakhutdinov N.F. , Simakov A.V. , Murzin D.Y.
One-Pot myrtenol Amination over Au Nanoparticles Supported on Different Metal Oxides
Applied Catalysis A: General. 2013. V.464-465. P.348-356. DOI: 10.1016/j.apcata.2013.06.013 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Mar 25, 2013
Accepted:	Jun 14, 2013
Published online:	Jun 24, 2013
Published print:	Aug 15, 2013

Web of science:	WOS:000323805300041
Scopus:	2-s2.0-84880078471
Elibrary:	20442769
Chemical Abstracts:	2013:1173805
Chemical Abstracts (print):	159:349627
OpenAlex:	W2010717571

DB	Citing
Web of science	37
Scopus	38
Elibrary	33
OpenAlex	38