Kinetic Modelling of One-Pot Myrtenol Amination over Au/ZrO2 Catalyst | Sciact - CRIS-система Института катализа

Kinetic Modelling of One-Pot Myrtenol Amination over Au/ZrO2 Catalyst Научная публикация

Конференция

XX International Conference on Chemical Reactors
03-07 дек. 2012 , Luxemburg

Журнал

Chemical Engineering Journal
ISSN: 1385-8947 , E-ISSN: 1873-3212

Вых. Данные

Год: 2014, Том: 238, Страницы: 164-171 Страниц : 8 DOI: 10.1016/j.cej.2013.09.007

Ключевые слова

Amination, Gold nanoparticles, Kinetics, Modeling, Myrtenol, One-pot

Авторы

Demidova Yu.S. ¹ , Simakova I.L. ¹ , Warna J. ² , Simakov A. ³ , Murzin D.Yu. ²

Организации

1	Boreskov Institute of Catalysis, 630090, Pr. Lavrentieva, 5, Novosibirsk, Russia
2	Process Chemistry Centre, Åbo Akademi University, FI-20500 Turku/Åbo, Finland
3	Centro de Nanociencias y Nanotecnología de la Universidad Nacional Autónoma de México, 22860 Ensenada, BC, Mexico

Информация о финансировании (3)

1	National Autonomous University of Mexico National Council of Science and Technology	179619
2	National Autonomous University of Mexico	203813
3	Российский фонд фундаментальных исследований	12-03-31623

A perspective environmentally-benign one-pot approach to the synthesis of complicated amines by alcohol amination was investigated in this work by mathematical modeling using myrtenol, which represents a natural terpene alcohol, and aniline as model substrates. The reaction was studied in the presence of Au/ZrO2 catalyst in the temperature range 413–453 K under kinetic control. Mechanistic model taking into account catalyst deactivation was developed from a proposed reaction mechanism and corresponding kinetic equations were derived. Kinetic model was compared with experimental data through numerical data fitting showing good correspondence.

Demidova Y.S. , Simakova I.L. , Warna J. , Simakov A. , Murzin D.Y.
Kinetic Modelling of One-Pot Myrtenol Amination over Au/ZrO2 Catalyst
Chemical Engineering Journal. 2014. V.238. P.164-171. DOI: 10.1016/j.cej.2013.09.007 WOS Scopus РИНЦ CAPlusCA OpenAlex

Опубликована online:	7 сент. 2013 г.
Опубликована в печати:	15 февр. 2014 г.

Web of science:	WOS:000331431500021
Scopus:	2-s2.0-84897086356
РИНЦ:	21869620
Chemical Abstracts:	2013:1537449
Chemical Abstracts (print):	160:87441
OpenAlex:	W2040623909

БД	Цитирований
Web of science	20
Scopus	21
РИНЦ	21
OpenAlex	21