Use of Re(C5H7O2) in Preparation of Catalysts for Olefin Metathesis Full article
| Journal |
Catalysis Letters
ISSN: 1011-372X , E-ISSN: 1572-879X |
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| Output data | Year: 1993, Volume: 19, Number: 2-3, Pages: 189-195 Pages count : 7 DOI: 10.1007/BF00771754 | ||
| Tags | cocatalysts, lead tetraethyl, Metathesis, organometallic catalysts | ||
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Abstract:
New catalysts for olefin metathesis are obtained upon interaction between rhenium trisacetylacetonate and
γ-Al2O3 surface. After high temperature treatment in flows of O2 and N2 and addition of organometallic compound as a cocatalyst the activity of the resulting catalyst exceeds that of known Re/Al2O3 catalysts prepared by impregnation. The catalysts exhibit maximal activity at a cocatalyst surface concentration of
3 × 10−7 mol/m2. Further increase of the cocatalyst concentration leads to deactivation.
Cite:
Klimov O.V.
, Khomyakova E.A.
, Startsev A.N.
Use of Re(C5H7O2) in Preparation of Catalysts for Olefin Metathesis
Catalysis Letters. 1993. V.19. N2-3. P.189-195. DOI: 10.1007/BF00771754 WOS Scopus РИНЦ ANCAN OpenAlex
Use of Re(C5H7O2) in Preparation of Catalysts for Olefin Metathesis
Catalysis Letters. 1993. V.19. N2-3. P.189-195. DOI: 10.1007/BF00771754 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Mar 2, 1993 |
| Accepted: | Mar 18, 1993 |
| Published print: | Jun 1, 1993 |
Identifiers:
| Web of science: | WOS:A1993LG90000010 |
| Scopus: | 2-s2.0-0343830287 |
| Elibrary: | 31187877 |
| Chemical Abstracts: | 1994:16376 |
| Chemical Abstracts (print): | 120:16376 |
| OpenAlex: | W2093825080 |