HREELS/TDS Study of NO Reaction with Hydrogen on Pt(100) Surface Full article
| Journal |
Catalysis Letters
ISSN: 1011-372X , E-ISSN: 1572-879X |
||
|---|---|---|---|
| Output data | Year: 1994, Volume: 28, Number: 2-4, Pages: 153-160 Pages count : 8 DOI: 10.1007/BF00806044 | ||
| Tags | autocatalysis, NO + H2 reaction, platinum, surface reconstruction | ||
| Authors |
|
||
| Affiliations |
|
Funding (2)
| 1 | Russian Foundation for Basic Research | 93-03-4793 |
| 2 | International Science Foundation | Ch3-6754-0935 |
Abstract:
NO adsorption on a Pt(100)-(hex) surface and NOads reaction with hydrogen at 300 K have been studied by HREELS, LEED, TDS and isothermal desorption. NO adsorbs in molecular form, its molecules gathering in islands with a high local coverage. Surface reconstruction into a (1 × 1) phase proceeds within the boundaries of islands. Reaction NO + H2 is performed via NOads previous heating in vacuum at Th = 375–425 K. Kinetics of NOads titration appears to be autocatalytic. Nitrogen is the major reaction product.
Cite:
Zemlyanov D.Y.
, Smirnov M.Y.
, Gorodetskii V.V.
HREELS/TDS Study of NO Reaction with Hydrogen on Pt(100) Surface
Catalysis Letters. 1994. V.28. N2-4. P.153-160. DOI: 10.1007/BF00806044 WOS Scopus РИНЦ ANCAN OpenAlex
HREELS/TDS Study of NO Reaction with Hydrogen on Pt(100) Surface
Catalysis Letters. 1994. V.28. N2-4. P.153-160. DOI: 10.1007/BF00806044 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Dec 6, 1993 |
| Published print: | Jun 1, 1994 |
| Accepted: | Jun 30, 1994 |
Identifiers:
| Web of science: | WOS:A1994PR85300004 |
| Scopus: | 2-s2.0-0043075653 |
| Elibrary: | 31107444 |
| Chemical Abstracts: | 1994:664790 |
| Chemical Abstracts (print): | 121:264790 |
| OpenAlex: | W2028661734 |