Isomerization of Bicyclic Terpene Epoxides into Allylic Alcohols without Changing of the Initial Structure | Sciact - CRIS-система Института катализа

Isomerization of Bicyclic Terpene Epoxides into Allylic Alcohols without Changing of the Initial Structure Научная публикация

Журнал

Journal of Molecular Catalysis A: Chemical
ISSN: 1381-1169

Вых. Данные

Год: 2014, Том: 388-389, Страницы: 162-166 Страниц : 5 DOI: 10.1016/j.molcata.2013.09.016

Ключевые слова

Gold, Isomerization, Pinene epoxide, Titania, Verbenol epoxide

Авторы

Demidova Yu.S. ¹ , Ardashov O.V. ² , Simakova O.A. ^3,4 , Simakova I.L. ¹ , Volcho K.P. ² , Salakhutdinov N.F. ² , Murzin D.Yu. ³

Организации

1	Boreskov Institute of Catalysis, pr. Lavrentieva, 5, 630090 Novosibirsk, Russia
2	Novosibirsk Institute of Organic Chemistry, pr. Lavrentieva, 9, 630090 Novosibirsk, Russia
3	Process Chemistry Centre, Åbo Akademi University, FI-20500 Turku/Åbo, Finland
4	School of Chemical & Biomolecular Engineering, Georgia Institute of Technology, 30332-0100 Atlanta, GA, USA

A novel method of (1S,2R,3R,5R)-6,6-dimethyl-4-methylenebicyclo[3.1.1]heptane-2,3-diol synthesis, which is a valuable intermediate in the synthesis of a perspective potent anti-Parkinson drugs, in the presence of TiO2 was proposed. Catalytic activity of TiO2 in the bicyclic terpene epoxides isomerization to corresponding allylic alcohols without changing of the initial structure was demonstrated, contrary to titania-supported Au catalysts which promoted rearrangement with predominant formation of a cyclopentene α-hydroxy ketone.

Demidova Y.S. , Ardashov O.V. , Simakova O.A. , Simakova I.L. , Volcho K.P. , Salakhutdinov N.F. , Murzin D.Y.
Isomerization of Bicyclic Terpene Epoxides into Allylic Alcohols without Changing of the Initial Structure
Journal of Molecular Catalysis A: Chemical. 2014. V.388-389. P.162-166. DOI: 10.1016/j.molcata.2013.09.016 WOS Scopus РИНЦ CAPlusCA OpenAlex

Поступила в редакцию:	1 июл. 2013 г.
Принята к публикации:	11 сент. 2013 г.
Опубликована online:	20 сент. 2013 г.
Опубликована в печати:	1 июл. 2014 г.

Web of science:	WOS:000337551800019
Scopus:	2-s2.0-84901324308
РИНЦ:	22049548
Chemical Abstracts:	2013:1610624
Chemical Abstracts (print):	161:39845
OpenAlex:	W2066430198

БД	Цитирований
Web of science	18
Scopus	19
РИНЦ	17
OpenAlex	19