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HREELS Study and Catalytic Significance of Low-Temperature Interaction of Isolated Carbon Atoms with Hydrogen on Pt(111) Full article

Journal Catalysis Letters
ISSN: 1011-372X , E-ISSN: 1572-879X
Output data Year: 1991, Volume: 8, Number: 1, Pages: 101-106 Pages count : 6 DOI: 10.1007/BF00764386
Tags SURFACE; ADSORPTION; MECHANISM; ACETYLENE
Authors Smirnov M.Yu. 1 , Gall N.R. 2 , Cholach A.R. 1 , Gorodetskii V.V. 1 , Tontegode A.Ya. 2 , Rut'kov E.V. 2 , Zemlyanov D.Yu. 1
Affiliations
1 Institute of Catalysis, Novosibirsk 630090, USSR
2 A.F. Ioffe Physical Technical Institute, Leningrad 194021, USSR

Abstract: Isolated atoms of carbon evaporated on to Pt(111) react with hydrogen atT⩾170 K to form methine species, characterized with vibrational modes v(CH) at 2960 and δ(CH) at 800 cm−1. The high reactivity of Cads is in line with their ability to take part as intermediates in the metanation reaction. CHads species are stable up toT ≈ 500 K; further heating leads to their dissociation accompanied by H2 desorption and formation of unreactive graphite-like islands.
Cite: Smirnov M.Y. , Gall N.R. , Cholach A.R. , Gorodetskii V.V. , Tontegode A.Y. , Rut'kov E.V. , Zemlyanov D.Y.
HREELS Study and Catalytic Significance of Low-Temperature Interaction of Isolated Carbon Atoms with Hydrogen on Pt(111)
Catalysis Letters. 1991. V.8. N1. P.101-106. DOI: 10.1007/BF00764386 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Nov 7, 1990
Accepted: Nov 12, 1990
Published print: Jan 1, 1991
Identifiers:
Web of science: WOS:A1991ET00900011
Scopus: 2-s2.0-0342591818
Elibrary: 31101442
Chemical Abstracts: 1991:407887
Chemical Abstracts (print): 115:7887
OpenAlex: W1976399980
Citing:
DB Citing
Web of science 13
Scopus 13
Elibrary 14
OpenAlex 14
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