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Possible Impact of Heterogeneous Photocatalysis on the Global Chemistry of the Earth's Atmosphere Review

Journal Catalysis Reviews: Science and Engineering
ISSN: 0161-4940 , E-ISSN: 1520-5703
Output data Year: 1994, Volume: 36, Number: 4, Pages: 617-644 Pages count : 28 DOI: 10.1080/01614949408013930
Tags TITANIUM-DIOXIDE; CARBON-DIOXIDE; AQUEOUS SUSPENSIONS; LIQUID PROPAN-2-OL; WATER; OXIDATION; TiO2; OXIDE; NITROGEN; POWDERS
Authors Zamaraev Kirill I. 1 , Khramov Michail I. 1 , Parmon Valentin N. 1
Affiliations
1 Boreskov Institute of Catalysis, Novosibirsk, 630090, Russia

Abstract: Photochemistry is recognized to be important for various physicochemical processes in the atmosphere, such as formation of the ozone layer and smogs, degradation of waste substances, etc. [1]. However, up to the present the emphasis in atmospheric photochemistry has been mainly on the study of photochemical reactions that occur with molecules directly excited by absorption of light quanta. However, the major components and impurities of the earth's atmosphere (such as nitrogen, oxygen, water, carbon dioxide, methane, methane halides, etc.) are totally transparent to most solar radiation. Electronically excited states of these molecules are formed only upon absorption of vacuum ultraviolet light quanta with energy hv ≥ 5 eV (i.e., with wavelength λ ≤ 200 nm). Only a small portion of the energy of solar light is found in this spectral region. In other words, most of the energy of the solar flux cannot participate in such direct photochemical reactions.
Cite: Zamaraev K.I. , Khramov M.I. , Parmon V.N.
Possible Impact of Heterogeneous Photocatalysis on the Global Chemistry of the Earth's Atmosphere
Catalysis Reviews: Science and Engineering. 1994. V.36. N4. P.617-644. DOI: 10.1080/01614949408013930 WOS Scopus РИНЦ РИНЦ ANCAN OpenAlex
Dates:
Published print: Nov 1, 1994
Published online: Sep 23, 2006
Identifiers:
Web of science: WOS:A1994PT89200002
Scopus: 2-s2.0-0028541985
Elibrary: 19126503 | 47582481
Chemical Abstracts: 1995:225721
Chemical Abstracts (print): 122:16008
OpenAlex: W1983052099
Citing:
DB Citing
Web of science 54
Scopus 61
Elibrary 51 52
OpenAlex 62
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