Propane Dehydrogenation over Pt-Sn Catalysts Full article
Conference |
C1-C3 hydrocarbons conversion : Workshop meeting 10-13 Sep 1991 , Красноярск |
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Journal |
Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308 |
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Output data | Year: 1992, Volume: 13, Number: 4, Pages: 655-658 Pages count : 4 DOI: 10.1016/0920-5861(92)80105-V | ||
Tags | X-RAY PHOTOELECTRON; ALUMINA CATALYSTS; PLATINUM; TIN; ALLOYS; STATE | ||
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Affiliations |
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Abstract:
The electronic state of Pt and Sn in alumina supported catalysts remains the subject of discussions for a long time. Some authors [I -3] have revealed that Sn in these catalysts has a Sno state and forms Pt-Sn alloys. It causes the inhibition of cracking reactions due to decreasing of Pt - hydrocarbon bond energy (ligand effect) or dilution of Pt surface by tin atoms (geometric effect). The others [4-7] provided evidence that Sn in supported catalysts is in Sn 2+ electronic condition and according to the surface model the Pt clusters locate on the tin aluminate surface 153.
In this paper we have tried to elucidate the role of Pt modification by Sn using a different manner of tin introducing into the catalyst.
Cite:
Yarusov I.B.
, Zatolokina E.V.
, Shitova N.B.
, Belyi A.S.
, Ostrovskii N.M.
Propane Dehydrogenation over Pt-Sn Catalysts
Catalysis Today. 1992. V.13. N4. P.655-658. DOI: 10.1016/0920-5861(92)80105-V WOS Scopus РИНЦ ANCAN OpenAlex
Propane Dehydrogenation over Pt-Sn Catalysts
Catalysis Today. 1992. V.13. N4. P.655-658. DOI: 10.1016/0920-5861(92)80105-V WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Published print: | Apr 6, 1992 |
Published online: | Jul 30, 2001 |
Identifiers:
Web of science: | WOS:A1992JD45800040 |
Scopus: | 2-s2.0-0027113535 |
Elibrary: | 31111105 |
Chemical Abstracts: | 1992:234923 |
Chemical Abstracts (print): | 116:234923 |
OpenAlex: | W1998054853 |