Modelling of a Periodically Operating Packed-Bed SO2 Oxidation Reactor at High Conversion | Sciact - CRIS-система Института катализа

Modelling of a Periodically Operating Packed-Bed SO2 Oxidation Reactor at High Conversion Научная публикация

Журнал

Chemical Engineering Science
ISSN: 0009-2509 , E-ISSN: 1873-4405

Вых. Данные

Год: 1994, Том: 49, Номер: 3, Страницы: 335-341 Страниц : 7 DOI: 10.1016/0009-2509(94)87005-5

Ключевые слова

VANADIUM CATALYSTS

Авторы

Silveston P.L. ¹ , Hudgins R.R. ¹ , Bogdashev S. ² , Vernijkovskaja N. ² , Matros Yu.Sh. ²

Организации

1	Department of Chemical Engineering, University of Waterloo, Waterloo, Ontario, Canada N2L 3Gl
2	Chemical Engineering Laboratory, Institute of Catalysis, Siberian Branch of the Russian Academy of Science, Novosibirsk, Russia

Информация о финансировании (1)

Natural Sciences and Engineering Research Council

Kinetic and mechanistic studies extending over a decade have led researchers at the Institute of Catalysis in Russia to a kinetic as well as a reactor model for SO2 oxidation capable of describing the rate of SO2 oxidation at high SO2 conversion and transient operating conditions. Using kinetic parameters and transport properties obtained for a Russian commercial catalyst, the Institute of Catalysis model was applied to simulate the experiments of Briggs in which the feed to a packed bed of an industrial, potassium-promoted, vanadia/silica catalyst was periodically switched from an SO3-SO2-O2-N2 mixture to air. These experiments displayed rapid temperature excursions on switching and SO2 conversions that approached the equilibrium limit. Good agreement of the simulation with the measurements of Briggs was obtained. This result suggests the Institute of Catalysis model is robust and will be widely applicable.

Silveston P.L. , Hudgins R.R. , Bogdashev S. , Vernijkovskaja N. , Matros Y.S.
Modelling of a Periodically Operating Packed-Bed SO2 Oxidation Reactor at High Conversion
Chemical Engineering Science. 1994. V.49. N3. P.335-341. DOI: 10.1016/0009-2509(94)87005-5 WOS Scopus РИНЦ CAPlusCA OpenAlex

Поступила в редакцию:	13 окт. 1992 г.
Принята к публикации:	21 июн. 1993 г.
Опубликована в печати:	1 янв. 1994 г.
Опубликована online:	4 окт. 2001 г.

Web of science:	WOS:A1994MU26100005
Scopus:	2-s2.0-0028374175
РИНЦ:	26578093
Chemical Abstracts:	1994:80459
Chemical Abstracts (print):	120:80459
OpenAlex:	W2019468726

БД	Цитирований
Web of science	17
Scopus	17
РИНЦ	17
OpenAlex	17