OD ESR Signals of Excess Electrons in Liquid Hydrocarbons Depending on the Geminate Recombination Parameters. Theory and Experiment Full article
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Chemical Physics
ISSN: 0301-0104 |
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| Output data | Year: 1985, Volume: 92, Number: 2-3, Pages: 381-387 Pages count : 7 DOI: 10.1016/0301-0104(85)85032-1 | ||||||
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Abstract:
The intensity of optically detected ESR (OD ESR) signals from radical-ion pairs in solution under ionizing irradiation has been investigated experimentally and theoretically as a function of the microwave power, the geminate recombination parameters, the diffusion coefficient, the distance distribution function of pairs, and the spin-lattice relaxation time. In line with theoritical predictions, the temperature dependence of an OD ESR signal has been shown to have a maximum depending on the microwave power. The experimental dependence has been measured for the system e− + triethylamine+ (TEA) in 3-methylpentane. Agreement between the theoretical and experimental dependences is discussed.
Cite:
Smirnov S.N.
, Rogov V.A.
, Shustov A.S.
, Sheberstov S.V.
, Panfilovitch N.V.
, Anisimov O.A.
, Molin Y.N.
OD ESR Signals of Excess Electrons in Liquid Hydrocarbons Depending on the Geminate Recombination Parameters. Theory and Experiment
Chemical Physics. 1985. V.92. N2-3. P.381-387. DOI: 10.1016/0301-0104(85)85032-1 WOS Scopus РИНЦ ANCAN OpenAlex
OD ESR Signals of Excess Electrons in Liquid Hydrocarbons Depending on the Geminate Recombination Parameters. Theory and Experiment
Chemical Physics. 1985. V.92. N2-3. P.381-387. DOI: 10.1016/0301-0104(85)85032-1 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Apr 26, 1984 |
| Published print: | Jan 15, 1985 |
| Published online: | Nov 16, 2001 |
Identifiers:
| Web of science: | WOS:A1985AAX0600019 |
| Scopus: | 2-s2.0-46549099951 |
| Elibrary: | 30886867 |
| Chemical Abstracts: | 1985:142014 |
| Chemical Abstracts (print): | 102:142014 |
| OpenAlex: | W2069219967 |