27Al, 1H NMR Studies of Supported LiAlH4 and Pd-LiAlH4 as Reagents for Dechlorination of Chlorobenzene Full article
| Journal |
Journal of Molecular Catalysis A: Chemical
ISSN: 1381-1169 |
||
|---|---|---|---|
| Output data | Year: 1995, Volume: 101, Number: 3, Pages: 237-241 Pages count : 5 DOI: 10.1016/1381-1169(95)00078-X | ||
| Tags | Chlorobenzene, Dechlorination, Hydrides, NMR, Palladium | ||
| Authors |
|
||
| Affiliations |
|
Abstract:
The reactivities of LiAlH4 and LiAlH4-Pd supported on porous carbon 'Sibunit' in dechlorination of chlorobenzene under mild conditions and their 1H, 27Al high resolution solid state NMR MAS spectra are reported. Supported hydrides demonstrate better reactivity compared with LiAlH4 in ether-toluene solution. 1H, and 27Al NMR MAS spectra of supported Pd-LiAlH4/Sibunit suggest the formation of complex hydrides on the surface.
Cite:
Simagina V.I.
, Mastikhin V.M.
, Yakovlev V.A.
, Stoyanova I.V.
, Likholobov V.A.
27Al, 1H NMR Studies of Supported LiAlH4 and Pd-LiAlH4 as Reagents for Dechlorination of Chlorobenzene
Journal of Molecular Catalysis A: Chemical. 1995. V.101. N3. P.237-241. DOI: 10.1016/1381-1169(95)00078-X WOS Scopus РИНЦ ANCAN OpenAlex
27Al, 1H NMR Studies of Supported LiAlH4 and Pd-LiAlH4 as Reagents for Dechlorination of Chlorobenzene
Journal of Molecular Catalysis A: Chemical. 1995. V.101. N3. P.237-241. DOI: 10.1016/1381-1169(95)00078-X WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Feb 7, 1994 |
| Accepted: | Mar 30, 1995 |
| Published print: | Aug 24, 1995 |
| Published online: | Dec 22, 1999 |
Identifiers:
| Web of science: | WOS:A1995RT56600009 |
| Scopus: | 2-s2.0-0001011835 |
| Elibrary: | 30814565 |
| Chemical Abstracts: | 1995:739469 |
| Chemical Abstracts (print): | 123:227461 |
| OpenAlex: | W2221625524 |