Study on the Mechanism of Ethylene Oxidation by a Nitrite Complex of Palladium in Chloroform Medium | Sciact - CRIS-system of Boreskov Institute of Catalysis

Study on the Mechanism of Ethylene Oxidation by a Nitrite Complex of Palladium in Chloroform Medium Full article

Journal

Journal of Molecular Catalysis (Continued after 1994 as Journal of Molecular Catalysis A: Chemical and Journal of Molecular Catalysis B: Enzymatic)
ISSN: 0304-5102

Output data

Year: 1986, Volume: 37, Number: 2-3, Pages: 177-188 Pages count : 12 DOI: 10.1016/0304-5102(86)85007-6

Tags

CATALYSIS; CATALYSTS - Palladium Compounds; ORGANIC COMPOUNDS; SPECTROSCOPY, INFRARED - Applications

Authors

Gusevskaya E.V. ¹ , Beck I.E. ¹ , Stepanov A.G. ¹ , Likholobov V.A. ¹ , Nekipelov V.M. ¹ , Yermakov Yu.I. ¹ , Zamaraev K.I. ¹

Affiliations

1	Institute of Catalysis

A detailed mechanism of ethylene oxidation by a palladium nitrite complex Pd(NO2)Cl(CH3CN)2 in chloroform solution is studied using IR and 1H NMR spectroscopy. Kinetic and spectral data obtained indicate the formation of a number of intermediates. The structure and routes of decomposition of the intermediates to end products are suggested.

Gusevskaya E.V. , Beck I.E. , Stepanov A.G. , Likholobov V.A. , Nekipelov V.M. , Yermakov Y.I. , Zamaraev K.I.
Study on the Mechanism of Ethylene Oxidation by a Nitrite Complex of Palladium in Chloroform Medium
Journal of Molecular Catalysis (Continued after 1994 as Journal of Molecular Catalysis A: Chemical and Journal of Molecular Catalysis B: Enzymatic). 1986. V.37. N2-3. P.177-188. DOI: 10.1016/0304-5102(86)85007-6 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Nov 20, 1985
Accepted:	Mar 21, 1986
Published print:	Oct 1, 1986
Published online:	Oct 2, 2001

Web of science:	WOS:A1986E458500006
Scopus:	2-s2.0-0022790229
Elibrary:	30953939
Chemical Abstracts:	1987:137780
Chemical Abstracts (print):	106:137780
OpenAlex:	W1983941656

DB	Citing
Web of science	11
Scopus	14
Elibrary	12
OpenAlex	10