Composition of the Active Component of Supported Vanadium-Magnesium Catalysts According to 51 NMR Data Full article
| Journal |
Journal of Molecular Catalysis (Continued after 1994 as Journal of Molecular Catalysis A: Chemical and Journal of Molecular Catalysis B: Enzymatic)
ISSN: 0304-5102 |
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| Output data | Year: 1989, Volume: 50, Number: 1, Pages: 55-65 Pages count : 11 DOI: 10.1016/0304-5102(89)80110-5 | ||
| Tags | Magnesium Compounds--Activity; Nuclear Magnetic Resonance--Applications; Spectroscopic Analysis--Applications; Vanadium Compounds--Activity | ||
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Abstract:
Vanadium-magnesium supported catalysts and model compounds (magnesium vanadates) have been studied with use of 51V NMR. It has been established that on the catalyst surface there exist isolated tetrahedral and octahedral vanadium species, their associated forms and magnesium orthovanadate. Their relative concentrations were determined by both the surface concentration of vanadium and the nature of modifying agents (such as SO42−). The influence of CO2 and H2O adsorption and catalyst reduction with butene-1 on the vanadium coordination state has been studied.
Cite:
Lapina O.B.
, Simakov A.V.
, Mastikhin V.M.
, Veniaminov S.A.
, Shubin A.A.
Composition of the Active Component of Supported Vanadium-Magnesium Catalysts According to 51 NMR Data
Journal of Molecular Catalysis (Continued after 1994 as Journal of Molecular Catalysis A: Chemical and Journal of Molecular Catalysis B: Enzymatic). 1989. V.50. N1. P.55-65. DOI: 10.1016/0304-5102(89)80110-5 WOS Scopus РИНЦ ANCAN OpenAlex
Composition of the Active Component of Supported Vanadium-Magnesium Catalysts According to 51 NMR Data
Journal of Molecular Catalysis (Continued after 1994 as Journal of Molecular Catalysis A: Chemical and Journal of Molecular Catalysis B: Enzymatic). 1989. V.50. N1. P.55-65. DOI: 10.1016/0304-5102(89)80110-5 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Jan 20, 1988 |
| Accepted: | Sep 26, 1988 |
| Published print: | Feb 23, 1989 |
| Published online: | Oct 2, 2001 |
Identifiers:
| Web of science: | WOS:A1989T208700009 |
| Scopus: | 2-s2.0-0024607033 |
| Elibrary: | 31089958 |
| Chemical Abstracts: | 1989:122319 |
| Chemical Abstracts (print): | 110:122319 |
| OpenAlex: | W2072067547 |