Study of the Mechanism of Ethylene Oxidation by Palladium(II) Complexes Containing Nitro and/or Nitrato Ligands in Chloroform Full article
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Journal of Molecular Catalysis (Continued after 1994 as Journal of Molecular Catalysis A: Chemical and Journal of Molecular Catalysis B: Enzymatic)
ISSN: 0304-5102 |
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| Output data | Year: 1989, Volume: 50, Number: 2, Pages: 167-179 Pages count : 13 DOI: 10.1016/0304-5102(89)85060-6 | ||
| Tags | ethylene oxidation palladium nitrogen oxide; nitropalladium ethylene oxidation mechanism; nitratopalladium ethylene oxidation mechanism; propylene oxidation palladium nitrogen oxide | ||
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Abstract:
Complexes of Pd(NOn)2−mClmL2 (where n = 2, 3; m = 0,1, 2; L= CH3CN, CD3CN) were synthesized and their reactivities towards ethylene and propylene oxidation in a chloroform medium were investigated. The detailed mechanism of ethylene oxidation by dinitro- and mono-nitrato complexes of palladium in chloroform solutions was studied by IR and 1H NMR spectroscopy. The structures and routes of decomposition of the intermediates to reaction end products are proposed.
Cite:
Beck I.E.
, Gusevskaya E.V.
, Stepanov A.G.
, Likholobov V.A.
, Nekipelov V.M.
, Yermakov Y.I.
, Zamaraev K.I.
Study of the Mechanism of Ethylene Oxidation by Palladium(II) Complexes Containing Nitro and/or Nitrato Ligands in Chloroform
Journal of Molecular Catalysis (Continued after 1994 as Journal of Molecular Catalysis A: Chemical and Journal of Molecular Catalysis B: Enzymatic). 1989. V.50. N2. P.167-179. DOI: 10.1016/0304-5102(89)85060-6 WOS Scopus РИНЦ ANCAN OpenAlex
Study of the Mechanism of Ethylene Oxidation by Palladium(II) Complexes Containing Nitro and/or Nitrato Ligands in Chloroform
Journal of Molecular Catalysis (Continued after 1994 as Journal of Molecular Catalysis A: Chemical and Journal of Molecular Catalysis B: Enzymatic). 1989. V.50. N2. P.167-179. DOI: 10.1016/0304-5102(89)85060-6 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Apr 7, 1988 |
| Accepted: | Jul 26, 1988 |
| Published print: | Mar 16, 1989 |
| Published online: | Oct 2, 2001 |
Identifiers:
| Web of science: | WOS:A1989T397100007 |
| Scopus: | 2-s2.0-0024621830 |
| Elibrary: | 31088132 |
| Chemical Abstracts: | 1989:496447 |
| Chemical Abstracts (print): | 111:96447 |
| OpenAlex: | W1996449233 |