Study of the Effect of Pr and Ho Ions on Pd/SiO2 Properties Using Catalysts Prepared via Supported Organometallic Complexes Full article
| Conference |
VI International Symposium on Relation between Homogeneous and Heterogeneous Catalysis 25-29 Sep 1989 , Pisa |
||
|---|---|---|---|
| Journal |
Journal of Molecular Catalysis (Continued after 1994 as Journal of Molecular Catalysis A: Chemical and Journal of Molecular Catalysis B: Enzymatic)
ISSN: 0304-5102 |
||
| Output data | Year: 1989, Volume: 55, Number: 1, Pages: 84-93 Pages count : 10 DOI: 10.1016/0304-5102(89)80244-5 | ||
| Tags | Carbon Monoxide--Absorption; Methanol--Synthesis; Organometallics; Spectroscopy, Infrared--Applications | ||
| Authors |
|
||
| Affiliations |
|
Abstract:
FT-IR and XPS methods have been used to study the formation, the state of the components and the forms of CO adsorption on (Pd + Pr)/SiO2 catalysts prepared from organometallic precursors. The catalysts contain finely dispersed particles of metallic Pd coordinated with Pr3+ ions. A correlation between the Eb value for the Pd 3d level of modified Pd and its turnover number (TON) activity in CH3OH synthesis has been demonstrated. The high activity of promoted Pd seems to be due to activation of CO molecules on mixed active sites consisting of Pd atoms and lanthanide ions.
Cite:
Nogin Y.N.
, Paukshtis E.A.
, Pashis A.V.
, Ryndin Y.A.
Study of the Effect of Pr and Ho Ions on Pd/SiO2 Properties Using Catalysts Prepared via Supported Organometallic Complexes
Journal of Molecular Catalysis (Continued after 1994 as Journal of Molecular Catalysis A: Chemical and Journal of Molecular Catalysis B: Enzymatic). 1989. V.55. N1. P.84-93. DOI: 10.1016/0304-5102(89)80244-5 WOS Scopus РИНЦ OpenAlex ANCAN
Study of the Effect of Pr and Ho Ions on Pd/SiO2 Properties Using Catalysts Prepared via Supported Organometallic Complexes
Journal of Molecular Catalysis (Continued after 1994 as Journal of Molecular Catalysis A: Chemical and Journal of Molecular Catalysis B: Enzymatic). 1989. V.55. N1. P.84-93. DOI: 10.1016/0304-5102(89)80244-5 WOS Scopus РИНЦ OpenAlex ANCAN
Dates:
| Published print: | Nov 1, 1989 |
| Published online: | Oct 2, 2001 |
Identifiers:
| ≡ Web of science: | WOS:A1989CG95900008 |
| ≡ Scopus: | 2-s2.0-0024768603 |
| ≡ Elibrary: | 31093300 |
| ≡ OpenAlex: | W1989314726 |
| ≡ Chemical Abstracts: | 1990:101833 |
| ≡ Chemical Abstracts (print): | 112:101833 |