Formation and Reactivity of Palladium Hydride Complexes, [(PPh3)3PdH]+ and [(PPh3)2Pd(μ-H)(μ-CO)Pd(PPh3)2]+, in Aqueous Trifluoroacetic Acid Solutions Full article
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Journal of Organometallic Chemistry
ISSN: 0022-328X |
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| Output data | Year: 1985, Volume: 289, Number: 2-3, Pages: 425-430 Pages count : 6 DOI: 10.1016/0022-328X(85)87419-2 | ||
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Abstract:
Interaction of H2 with P2PdX2 complex (P = PPh3, X = CF3COO) in aqueous trifluoroacetic acid solution at 70°C in excess triphenylphosphine results in the formation of the palladium hydride complex [P3PdH]+. The same complex is formed by protonation of PdP4 at 25°C in aqueous CF3COOH. When treated by carbon monoxide, [P3RdH]+ is changed to the binuclear palladium carbonyl hydride complex [P2Pd(μ-H)(μ-CO)PdP2]+.
Cite:
Zudin V.N.
, Chinakov V.D.
, Nekipelov V.M.
, Likholobov V.A.
, Yermakov Y.I.
Formation and Reactivity of Palladium Hydride Complexes, [(PPh3)3PdH]+ and [(PPh3)2Pd(μ-H)(μ-CO)Pd(PPh3)2]+, in Aqueous Trifluoroacetic Acid Solutions
Journal of Organometallic Chemistry. 1985. V.289. N2-3. P.425-430. DOI: 10.1016/0022-328X(85)87419-2 WOS Scopus РИНЦ ANCAN OpenAlex
Formation and Reactivity of Palladium Hydride Complexes, [(PPh3)3PdH]+ and [(PPh3)2Pd(μ-H)(μ-CO)Pd(PPh3)2]+, in Aqueous Trifluoroacetic Acid Solutions
Journal of Organometallic Chemistry. 1985. V.289. N2-3. P.425-430. DOI: 10.1016/0022-328X(85)87419-2 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Dec 20, 1984 |
| Published print: | Jul 9, 1985 |
| Published online: | May 9, 2001 |
Identifiers:
| Web of science: | WOS:A1985AMF5900020 |
| Scopus: | 2-s2.0-0001687461 |
| Elibrary: | 30810382 |
| Chemical Abstracts: | 1986:109902 |
| Chemical Abstracts (print): | 104:109902 |
| OpenAlex: | W2004668828 |