Abstract: The most probable intermediate formed by interaction of CO and C2H4 with [(PPh3)3PtH]+ (I), in the synthesis of diethyl ketone from C2H4, CO and H2 under action of the catalytic system (PPh3)2Pt(OAc)2/PPh3/CF3COOH has been studied by 1H, 13C, 31P NMR spectroscopy. Complex I readily reacts with CO in CF3COOH solutions to form a carbonyl hydride complex trans-[(PPh3)2Pt(CO)H]+ (II). In contrast to I, II undergoes ethylene insertion at the PtH bond in the presence of a catalytic additive Sn(OAc)2. The carbonyl ethyl complex trans[(PPh3)2Pt(CO)C2-H5)]+ (III) formed quantitatively from this insertion is stable to isomerization to the corresponding complex indicating that the carbonylation of the Pt-ethyl bond is the rate-determining step of the diethyl ketone synthesis.

Cite: Chinakov V.D. , Il'inich G.N. , Zudin V.N. , Likholobov V.A. , Nekipelov V.M.
Study of the Interaction of Platinum Hydride Complex [(PPh3)3PtH]+ with Carbon Monoxide and Ethylene in Trifluoroacetic Acid Solutions
Journal of Organometallic Chemistry. 1989. V.366. N3. P.421-425. DOI: 10.1016/0022-328X(89)87192-X WOS Scopus РИНЦ ANCAN OpenAlex

Dates:

Submitted:	Oct 5, 1988
Published print:	May 2, 1989
Published online:	Apr 16, 2001

Identifiers:

Web of science:	WOS:A1989U596100014
Scopus:	2-s2.0-0344204182
Elibrary:	31097964
Chemical Abstracts:	1990:98787
Chemical Abstracts (print):	112:98787
OpenAlex:	W2049575524

Citing:

DB	Citing
Web of science	9
Scopus	9
Elibrary	8
OpenAlex	7

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