Different Nature of Outer-Sphere Complex Formation between Chloroform and bis-(N-phenyl-salicylaldiminate)Cu(II) and Its Adduct with Pyridine | Sciact - CRIS-system of Boreskov Institute of Catalysis

Different Nature of Outer-Sphere Complex Formation between Chloroform and bis-(N-phenyl-salicylaldiminate)Cu(II) and Its Adduct with Pyridine Full article

Journal

Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779

Output data

Year: 1982, Volume: 23, Number: 6, Pages: 956-958 Pages count : 3 DOI: 10.1007/BF00746549

Tags

Physical Chemistry; Inorganic Chemistry; Chloroform; Pyridine; Adduct

Authors

Talsi E.P. ¹ , Nekipelov V.M. ¹ , Kozyrev N.V. ¹ , Zamaraev K.I. ¹

Affiliations

1	Institute of Catalysis, Siberian Branch, Academy of Sciences of the USSR

The coordination of CHCI3 to Cu(Salim)a and Cu(Salim)2Py at 25oC has been studied using NMR. It was found that, in the complexes with Cu(Salim)2, the CHCI3 molecules are arranged out of the plane of the chelate while, with Cu(Salim)2Py, chloroform also forms equatorial outer-sphere complexes. The results are explained by the fact that the planar structure of the chelate is distorted during the axial coordination of pyridine as a result of which the formation of hydrogen bonds between the oxygen atoms of the complex and the hydrogen atoms of the CHCI3 molecules becomes possible.

Talsi E.P. , Nekipelov V.M. , Kozyrev N.V. , Zamaraev K.I.
Different Nature of Outer-Sphere Complex Formation between Chloroform and bis-(N-phenyl-salicylaldiminate)Cu(II) and Its Adduct with Pyridine
Journal of Structural Chemistry. 1982. V.23. N6. P.956-958. DOI: 10.1007/BF00746549 WOS Scopus РИНЦ OpenAlex

Талзи Е.П. , Некипелов В.М. , Козырев Н.В. , Замараев К.И.
Различный характер внешнесферного комплексообразования хлороформа с бис (N-фенил-салицилальдиминатом)Cu(II) и его аддуктом с пиридином
Журнал структурной химии. 1982. Т.23. №6. С.158-160. РИНЦ ANCAN

Submitted:	Dec 1, 1981
Published print:	Nov 1, 1983

Web of science:	WOS:A1982QZ52700022
Scopus:	2-s2.0-34250147545
Elibrary:	30669653
OpenAlex:	W2075125804

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