A Study of Polyhedral Octa (organosilasesquioxanes) by High-Resolution NMR at the 13C and 29Si Nuclei in the Solid State Full article
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Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779 |
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| Output data | Year: 1982, Volume: 23, Number: 3, Pages: 345-348 Pages count : 4 DOI: 10.1007/BF00753468 | ||||||
| Tags | Physical Chemistry; Inorganic Chemistry; Solid State | ||||||
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Abstract:
Polyhedral octa(organosilasesquioxanes) (RSiO1.s)8, where R = CH3, C2H5, or C2H3, have been studied by high-resolution NMR at the 13C and 29Si nuclei in the solid state. A correspondence has been established between the nonequivalence of the silicon atoms and the distortion of the silicon-oxygen framework of the molecule.
An explanation has been given for the nature of the splitting of the signals of the B-carbon atoms in the 13C NMR spectra in the ethyl and vinyl derivatives.
Cite:
Gorsh L.E.
, Shubin A.A.
, Nekipelov V.M.
, Kanev A.N.
A Study of Polyhedral Octa (organosilasesquioxanes) by High-Resolution NMR at the 13C and 29Si Nuclei in the Solid State
Journal of Structural Chemistry. 1982. V.23. N3. P.345-348. DOI: 10.1007/BF00753468 WOS Scopus РИНЦ OpenAlex
A Study of Polyhedral Octa (organosilasesquioxanes) by High-Resolution NMR at the 13C and 29Si Nuclei in the Solid State
Journal of Structural Chemistry. 1982. V.23. N3. P.345-348. DOI: 10.1007/BF00753468 WOS Scopus РИНЦ OpenAlex
Original:
Горш Л.Э.
, Шубин А.А.
, Некипелов В.М.
, Канев А.Н.
Изучение полиэдрических окта(органилсилсесквиоксанов) с помощью ЯМР высокого разрешения на ядрах 13C и 29Si в твердом теле
Журнал структурной химии. 1982. Т.23. №3. С.26-29. РИНЦ ANCAN
Изучение полиэдрических окта(органилсилсесквиоксанов) с помощью ЯМР высокого разрешения на ядрах 13C и 29Si в твердом теле
Журнал структурной химии. 1982. Т.23. №3. С.26-29. РИНЦ ANCAN
Dates:
| Submitted: | Dec 15, 1981 |
| Published print: | May 1, 1982 |
Identifiers:
| Web of science: | WOS:A1982PW27200003 |
| Scopus: | 2-s2.0-34250149694 |
| Elibrary: | 30989920 |
| OpenAlex: | W2022271572 |