Catalysts of the Gas-Phase Hydroformylation of Propylene Prepared by the Pyrolysis of Co2(CO)8 on Oxide Supports | Sciact - CRIS-system of Boreskov Institute of Catalysis

Catalysts of the Gas-Phase Hydroformylation of Propylene Prepared by the Pyrolysis of Co2(CO)8 on Oxide Supports ArticleGenre_short.LETTER

Journal

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Output data

Year: 1982, Volume: 23, Number: 3, Pages: 644-645 Pages count : 2

Authors

Moroz B.L. ¹ , Lisitsyn A.S. ¹ , Semikolenov V.A. ¹ , Likholobov V.A. ¹ , Ermakov Y.I. ¹

Affiliations

1	Institute of Catalysis, Siberian Branch U.S.S.R. Academy of Sciences

Impregnation of SiO2, Al2O3, La2O3, TiO2, and MgO with a pentane solution of Co2(CO)8, followed by rapid pyrolysis in a vacuum at 530 K, gave active catalysts for propylene hydroformylation. The most active catalyst contained 0.4% Co on SiO2. Selectivities for unbranched products ranged from 54 to 89%. The main products (48-89%) were butanols, formed by reduction of butyraldehydes.

Moroz B.L. , Lisitsyn A.S. , Semikolenov V.A. , Likholobov V.A. , Ermakov Y.I.
Catalysts of the Gas-Phase Hydroformylation of Propylene Prepared by the Pyrolysis of Co2(CO)8 on Oxide Supports
Kinetics and Catalysis. 1982. V.23. N3. P.644-645. WOS РИНЦ

Мороз Б.Л. , Лисицын А.С. , Семиколенов В.А. , Лихолобов В.А. , Ермаков Ю.И.
Катализаторы газофазного гидроформилирования пропилена, приготовленные пиролизом Сo2(СО)8 на окисных носителях
Кинетика и катализ. 1982. Т.23. №3. С.762-763. РИНЦ ANCAN

Submitted:	Dec 29, 1981
Published print:	May 1, 1982

Web of science:	WOS:A1982PX94400029
Elibrary:	30640756

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Catalysts of the Gas-​Phase Hydroformylation of Propylene Prepared by the Pyrolysis of Co2(CO)​8 on Oxide Supports ArticleGenre_short.LETTER

Catalysts of the Gas-Phase Hydroformylation of Propylene Prepared by the Pyrolysis of Co2(CO)8 on Oxide Supports ArticleGenre_short.LETTER