Oxidation of Carbon Monoxide by Strong Oxidizing Agents in the Presence of Pd(II) Complexes Full article
| Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
||
|---|---|---|---|
| Output data | Year: 1984, Volume: 25, Number: 5, Pages: 930-935 Pages count : 6 | ||
| Authors |
|
||
| Affiliations |
|
Abstract:
The kinetics of the catalytic oxidation of CO by Cr2O7 2- and Ce(IV) ions in the presence of an aquacomplex of Pd(II), as well as the kinetics of the stoichiometric reduction of Pd(II)aq by carbon monoxide, were studied. A comparison of the kinetic functions of these reactions shows that the limiting step of the catalytic oxidation of CO is the reduction of aqua- or chloride complexes of Pd(II) by carbon monoxide. It is suggested that the low rate of the catalytic reaction in the presence of strong oxidizing agents left bracket Cr2O7 2- and Ce(IV) right bracket is explained by the rapid oxidation of Pd(0), which prevents the formation of more active carbonyl complexes of partially reduced palladium.
Cite:
Zhizhina E.G.
, Kuznetsova L.I.
, Matveev K.I.
Oxidation of Carbon Monoxide by Strong Oxidizing Agents in the Presence of Pd(II) Complexes
Kinetics and Catalysis. 1984. V.25. N5. P.930-935. WOS Scopus РИНЦ
Oxidation of Carbon Monoxide by Strong Oxidizing Agents in the Presence of Pd(II) Complexes
Kinetics and Catalysis. 1984. V.25. N5. P.930-935. WOS Scopus РИНЦ
Original:
Жижина Е.Г.
, Кузнецова Л.И.
, Матвеев К.И.
Окисление окиси углерода сильными окислителями в присутствии комплексов Pd(II)
Кинетика и катализ. 1984. Т.25. №5. С.1095-1100. РИНЦ ANCAN
Окисление окиси углерода сильными окислителями в присутствии комплексов Pd(II)
Кинетика и катализ. 1984. Т.25. №5. С.1095-1100. РИНЦ ANCAN
Dates:
| Submitted: | Jul 29, 1983 |
| Published print: | Sep 1, 1984 |
Identifiers:
| Web of science: | WOS:A1984AHD4600012 |
| Scopus: | 2-s2.0-0021484475 |
| Elibrary: | 30602846 |