New Cobalt Catalysts for the Synthesis of Diethyl Ketone from Ethylene, Carbon-Monoxide, and Water | Sciact - CRIS-system of Boreskov Institute of Catalysis

New Cobalt Catalysts for the Synthesis of Diethyl Ketone from Ethylene, Carbon-Monoxide, and Water ArticleGenre_short.LETTER

Journal

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Output data

Year: 1984, Volume: 25, Number: 2, Pages: 424-425 Pages count : 2

Authors

Startseva L.Y. ¹ , Semikolenov V.A. ¹ , Lisitsyn A.S. ¹ , Likholobov V.A. ¹ , Ermakov Y.I. ¹

Affiliations

1	Institute of Catalysis, Siberian Branch U.S.S.R. Academy of Sciences

In testing the possibility of employing the catalysts used to carry out a hydrocarboxylation process, the authors found that the catalyst prepared by rapid pyrolysis of Co2(CO)8 adsorbed on the surface of a carbon support converted a C2H4:CO:H2O gas mixture into diethyl ketone at an appreciable rate even at 423 degree K. When catalysts obtained by rapid pyrolysis of Co2(CO)8 adsorbed on oxide supports were used, the predominant process was hydrogenation of ethylene to ethane. In a number of cases, traces of propionic aldehyde, ethyl propionate, and diethyl ketone were found in the reaction products. The unusual catalytic properties of the Co/carbon-support sample are explained by the particular state of the deposited metal.

Startseva L.Y. , Semikolenov V.A. , Lisitsyn A.S. , Likholobov V.A. , Ermakov Y.I.
New Cobalt Catalysts for the Synthesis of Diethyl Ketone from Ethylene, Carbon-Monoxide, and Water
Kinetics and Catalysis. 1984. V.25. N2. P.424-425. WOS Scopus РИНЦ

Старцева Л.Я. , Семиколенов В.А. , Лисицын А.С. , Лихолобов В.А. , Ермаков Ю.И.
Новые кобальтовые катализаторы синтеза диэтилкетона из этилена, окиси углерода и воды
Кинетика и катализ. 1984. Т.25. №2. С.506. РИНЦ ANCAN

Submitted:	Sep 23, 1983
Published print:	Mar 1, 1984

Web of science:	WOS:A1984TS58800026
Scopus:	2-s2.0-0021390717
Elibrary:	30602980

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Web of science	1
Scopus	1
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