Influence of the Nature of the Oxidizing-Agents on the Mechanism of the Oxidation of Carbon-Monoxide in the Presence of an Aqua Complex of Palladium(II) | Sciact - CRIS-system of Boreskov Institute of Catalysis

Influence of the Nature of the Oxidizing-Agents on the Mechanism of the Oxidation of Carbon-Monoxide in the Presence of an Aqua Complex of Palladium(II) Full article

Journal

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Output data

Year: 1985, Volume: 26, Number: 2, Pages: 404-408 Pages count : 5

Authors

Zhizhina E.G. ¹ , Matveev K.I. ¹ , Kuznetsova L.I. ¹

Affiliations

1	Institute of Catalysis, Siberian Branch U.S.S.R. Academy of Sciences

The kinetics of CO oxidation was studied in the presence of aquo complexes of Pd(II), VO2+, Fe3+, and heteropoly-acids H3PMO12O40, H4PMo11VO40, and H4PW11VO40. A comparison of the present and published results on oxidation with strong oxidizing agents, such as Cr2O72-, of Ce4+, reveals that for a fast oxidation, the oxidation potential should be 0.7-1.0 V. The intermediate carbonyl complexes of partially reduced Pd are the most active catalysts of the oxidation.

Zhizhina E.G. , Matveev K.I. , Kuznetsova L.I.
Influence of the Nature of the Oxidizing-Agents on the Mechanism of the Oxidation of Carbon-Monoxide in the Presence of an Aqua Complex of Palladium(II)
Kinetics and Catalysis. 1985. V.26. N2. P.404-408. WOS РИНЦ

Жижина Е.Г. , Матвеев К.И. , Кузнецова Л.И.
Влияние природы окислителей на механизм процесса окисления оксида углерода в присутствии аквакомплекса палладия (II)
Кинетика и катализ. 1985. Т.26. №2. С.461-465. РИНЦ ANCAN

Submitted:	Oct 13, 1983
Published print:	Mar 1, 1985

Web of science:	WOS:A1985AUZ1800017
Elibrary:	30603111

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