Study of the Heats of Adsorption of Reactants in the Claus Process in a Series of Oxide Catalysts | Sciact - CRIS-система Института катализа

Study of the Heats of Adsorption of Reactants in the Claus Process in a Series of Oxide Catalysts Научная публикация

Журнал

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Вых. Данные

Год: 1991, Том: 31, Номер: 5 pt 2, Страницы: 1051-1057 Страниц : 7

Ключевые слова

Adsorption--Thermodynamics; Catalysts--Activity; Oxides--Spectroscopic Analysis; Spectroscopy, Infrared--Applications; Sulfur Compounds--Adsorption

Авторы

Marshneva V.I. ¹ , Dubkov K.A. ¹ , Mokrinskii V.V. ¹ , Paukshtis E.A. ¹ , Davydov A.A. ¹

Организации

1	Institute of Catalysis, Siberian Branch, Academy of Sciences of the USSR

The heats of adsorption of the reactants H2S and SO2 were measured in a series of oxide catalysts which work stably in the Claus reaction. It was shown that an increase in the specific steady-state activity is observed on the oxides with a decrease in the heats of adsorption of both reactants. The heat of adsorption of SO2 on the most active V2O5 catalyst is approximately one-half of the change in the enthalpy in the Claus reaction. The forms of adsorption of SO2 and H2S were identified in comparing the adsorption data with the IR spectroscopic data.

Marshneva V.I. , Dubkov K.A. , Mokrinskii V.V. , Paukshtis E.A. , Davydov A.A.
Study of the Heats of Adsorption of Reactants in the Claus Process in a Series of Oxide Catalysts
Kinetics and Catalysis. 1991. V.31. N5 pt 2. P.1051-1057. WOS Scopus РИНЦ

Маршнева В.И. , Дубков К.А. , Мокринский В.В. , Паукштис Е.А. , Давыдов А.А.
Исследование теплот адсорбции реагентов процесса Клауса в ряду оксидных катализаторов
Кинетика и катализ. 1990. Т.31. №5. С.1199-1205. РИНЦ CAPlusCA

Поступила в редакцию:	13 дек. 1988 г.
Опубликована в печати:	1 апр. 1991 г.

Web of science:	WOS:A1990FM58000008
Scopus:	2-s2.0-0026137154
РИНЦ:	31150335

БД	Цитирований
Scopus	1
РИНЦ	1