IR Spectroscopic Study of the Mechanism of Deep Oxidation of 2-Propanol on Cupric Oxide under Catalytic Reaction conditions | Sciact - CRIS-система Института катализа

IR Spectroscopic Study of the Mechanism of Deep Oxidation of 2-Propanol on Cupric Oxide under Catalytic Reaction conditions Научная публикация

Журнал

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Вых. Данные

Год: 1992, Том: 33, Номер: 1, Страницы: 107-113 Страниц : 7

Ключевые слова

ADSORPTION; ACETONE; MgO; NiO

Авторы

Dobrynkin N.M. ¹ , Davydov A.A. ¹ , Budneva A.A. ¹ , Popovskii V.V. ¹ , Rogov V.A. ¹ , Serebryakov V.F. ¹

Организации

1	Institute of Catalysis, Siberian Branch, Academy of Sciences of the USSR

The spectrokinetic method was used to study surface compounds and the kinetics of their conversion, to establish the structure of intermediate surface forms and the sequence of their conversions, and to determine kinetic parameters of the individual steps. It was shown that under the conditions of a catalytic reaction a successive chain of conversions of surface structures is realized: isopropylate ---- --> adsorbed acetone structures --- --> carboxylate + formate ---- --> carbon dioxide, with the step of oxidation of carboxylate structures being the limiting step.

Dobrynkin N.M. , Davydov A.A. , Budneva A.A. , Popovskii V.V. , Rogov V.A. , Serebryakov V.F.
IR Spectroscopic Study of the Mechanism of Deep Oxidation of 2-Propanol on Cupric Oxide under Catalytic Reaction conditions
Kinetics and Catalysis. 1992. V.33. N1. P.107-113. WOS РИНЦ

Добрынкин Н.М. , Давыдов А.А. , Буднева А.А. , Поповский В.В. , Рогов В.А. , Серебряков В.Ф.
ИК-спектроскопическое исследование механизма глубокого окисления пропанола-2 на оксиде меди в условиях осуществления каталитической реакции
Кинетика и катализ. 1992. Т.33. №1. С.133-141. РИНЦ CAPlusCA

Поступила в редакцию:	2 янв. 1990 г.
Опубликована в печати:	1 янв. 1992 г.

Web of science:	WOS:A1992JP32300001
РИНЦ:	30598186

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